A 20-tablet sample of soluble saccharin was treated with 20.00 mL of 0.08181 N AgNO3. After removal of the solid, titration of the filtrate and washings required 2.81 mL of 0.04124 N KSCN. Calculate the average number of milligrams of saccharin (205.17 g/mol) in each tablet.
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A 20-tablet sample of soluble saccharin was treated with 20.00 mL of 0.08181 N AgNO3. After removal of the solid, titration of the filtrate and washings required 2.81 mL of 0.04124 N KSCN. Calculate the average number of milligrams of saccharin (205.17 g/mol) in each tablet.
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- An analyte solution was prepared using 1.1278 g of a diprotic acid and 25.0 mL of distilled water. A 5.0 mL aliquot was then taken and diluted to 50.0mL. During titration, it required 19.4 mL of a 0.0356 M standardized NaOH solution to reach the end point. a.) What is the molarity of the undiluted analyte solution? b.) What is the molecular weight of the diprotic acid?3. A 0.1093-g sample of impure Na2CO3 was analyzed by the Volhard method. After adding 50.00 mL of 0.06911 M AgNO3, the sample was back titrated with 0.05781 M KSCN, requiring 27.36 mL to reach the end point. Report the purity of the Na2CO3 sample.A 1.5000-g sample of cereals was analyzed for nitrogen using the Kjeldahl procedure. The receiving flask contained 69 mL of 0.02 M HCl. After the ammonia was collected, the solution was titrated with 0 M NaOH, requiring 11.72 mL to reach the methyl red endpoint. Calculate and percent protein in the sample (f=5.70). Ans. in 3 SFs
- A 1.250 g sample of cheese was subjected to a Kjeldahl analysis to determine the amount of protein. The sample was digested, the nitrogen is oxidized to NH₄⁺, and was then converted to NH₃ with NaOH, and distilled into a collection flask containing 50.00 mL of 0.1050 M HCl. The excess HCl is back titrated with 0.1175 M NaOH, this required 21.65 mL to reach the bromothymol blue end point. A. How many moles of N is present in the cheese sample? B. Report the %N of the cheese sample. C. Report the %protein of the cheese sample, assuming that there are 6.4 grams of protein for every gram of nitrogenA 1.250 g sample of cheese was subjected to a Kjeldahl analysis to determine the amount of protein. The sample was digested, the nitrogen is oxidized to NH₄⁺, and was then converted to NH₃ with NaOH, and distilled into a collection flask containing 50.00 mL of 0.1050 M HCl. The excess HCl is back titrated with 0.1175 M NaOH, this required 21.65 mL to reach the bromothymol blue end point. What is the reaction for the digestion of the limestone sample A. 2 NaOH + CaCO₃ ⇌ Na₂CO₃ + Ca(OH)₂ B. 2 HCl + CaCO₃ ⇌ CaCl₂ + H₂O + CO₂ C. CaCO₃ ⇌ CaO + CO₂ D. NaOH + HCl ⇌ NaCl + H₂OA 1.250 g sample of cheese was subjected to a Kjeldahl analysis to determine the amount of protein. The sample was digested, the nitrogen is oxidized to NH₄⁺, and was then converted to NH₃ with NaOH, and distilled into a collection flask containing 50.00 mL of 0.1050 M HCl. The excess HCl is back titrated with 0.1175 M NaOH, this required 21.65 mL to reach the bromothymol blue end point. What is the reaction for the back titration for this analysis? a. NH₄⁺ + NaOH ⇌ NH₃ + H₂O + Na⁺ b. NaOH + HCl ⇌ NaCl + H₂O c. NH₃ + HCl ⇌ NH₄⁺ + Cl⁻ d. N₂ + 3 H₂ ⇌ 2 NH₃ How many moles of N is present in the cheese sample? a. 544 x 10⁻³ b. 706 x 10⁻³ c. 250 x 10⁻³ d. 794 x 10⁻³ Report the %N of the cheese sample. a. 851% b. 884% c. 033% d. 736%
- A 1.219-g containing (NH4)2SO4, NH4NO3, and nonreactive substances was diluted to 200 mL in a volumetric flask. A 50.00-mL aliquot was made basic with strong alkali, and the liberated NH3 was distilled into 30.00-mL of 0.08421 M HCl. The excess HCl required 10.17 mL of 0.08802 M NaOH. A 25-mL aliquot of the sample was made alkaline after the addition of Devarda’s alloy, and the NO3- was reduced to NH3. The NH3 from both the NH4+ and NO3- was then distilled into 30.00 mL of the standard acid and back titrated with 14.16 mL of base. Calculate the percentage of (NH4)2SO4 and NH4NO3 in the sample.For breakfast, the nihilistic Rick Sanchez ate 100 g of cereal mixed with 20 g of milk. A 1.500 g sample of the same cereal was analyzed using the Kjeldahl method, and the liberated NH3 was distilled into 50 mL of a 0.0227 M HCl solution, and back-titrated with 2.85 mL of 0.0112 M NaOH solution. A 1.100 g sample of milk was also analyzed, and the liberated NH3 was distilled into 55 mL of a 0.0234 M HCl solution, and back-titrated with a 3.10 mL of 0.0121 M NaOH. Use the values: MM N=14.07 g/mol. meat= 6.25 dairy= 6.38 cereal= 5.70 What is the % protein in the cereal sample? What is the % protein in the milk sample?For breakfast, the nihilistic Rick Sanchez ate 100 g of cereal mixed with 20 g of milk. A 1.500 g sample of the same cereal was analyzed using the Kjeldahl method, and the liberated NH3 was distilled into 50 mL of a 0.0227 M HCl solution, and back-titrated with 2.85 mL of 0.0112 M NaOH solution. A 1.100 g sample of milk was also analyzed, and the liberated NH3 was distilled into 55 mL of a 0.0234 M HCl solution, and back-titrated with a 3.10 mL of 0.0121 M NaOH. Use the values: MM N=14.07 g/mol. meat= 6.25 dairy= 6.38 cereal= 5.70 1. What is the % protein in the cereal sample? a. 5.90% protein b. 10.21% protein c. 11.80% protein d. 20.42% protein 2. What is the % protein in the milk sample? a. 5.90% protein b. 10.21% protein c. 11.80% protein d. 20.42% protein 3. How many grams of protein did Rick consume over-all? a. 3.749 g b. 7.942 g c. 5.901 g d. 10.21 g
- Standardization of EDTA was done using MgSO4 standard wherein a 50-mL aliquot of solution obtained from 0.480 g MgSO4 in 500 mL needed 39.4 mL of the EDTA solution to reach the endpoint. Determine how many milligrams of CaCO3 will react per mL of this EDTA solution.2.4414 g sample containing KCl, K2SO4 and inert materials was dissolved in sufficient water to give 250 mL of solution. A Mohr titration of a 50 mL aliquot required 41.36 mL of 0.05818 M AgNO3. A second 50mL aliquot was treated with 40 mL of 0.1083M NaB(C6H5)4. The reaction is NaB(C6H5)4+ K+ KB(C6H5)4(s) + Na+. The solid was filtered, redissolved in acetone, and titrated with 49.98mL of the AgNO3 solution according to the reaction KB(C6H5)4 + Ag+ AgB(C6H5)4(s) + K+. Calculate the percentage of KCl and K2SO4 in the sample.In order to adjust the Potassium Permanganate solution, 0.0544g Na2C2O4 was taken and necessary experimental procedures were performed on it and the titrant consumption was found to be 7.9 mL. What is the KMnO4 concentration?