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- Aspirin powder = 0.8110g MW of Aspirin = 180g.mol-1 Volume of 0.5N HCl consumed in back titration = 23.50mL Volume of 0.5N HCl consumed in blank titration = 44.50mL Percent purity (USP/NF) = Aspirin tablets contain NLT 90.0% and NMT 110.0% of the labeled amount of aspirin (C9H8O4) What is the calculated weight (in grams) of pure aspirin?..3What is the ratio strength of benzalkonium chloride in a nasal spray that contains 125 µg/mL of the ingredient? a 1:8 b 1:80 c 1:800 d 1:8000An unknown sample of Cu2+gave an absorbance of 0.262. Then 1.00 mL of solution containing 100 ppm (ug/mL)Cu2+was mixed with 95.0 mL of the unknown and the mixture was diluted to 100 mL in a volumetric flask with deionized water. The absorbanceof the new solution was 0.500. a.Denoting the initial unknown concentrationas [Cu2+]i,write an expression for the final concentrationafter dilution [Cu2+] b.Find [Cu2+]in the unknown.
- A solution of Ca(OH)2 (FM = 74.09) was used in determining the equivalent weight of an unknown acid. To do so, the said solution was standardized against 0.1235 g KHP (FM = 204.22), requiring 7.45 mL to reach the phenolphthalein endpoint. On the other hand, a 0.0543 g unknown acid requires 12.85 mL standard Ca(OH)2 to reach the desired endpoint.a. Calculate the standard normality of Ca(OH)2.b. Calculate the equivalent weight of the unknown acid.c. From the information in the table, what is the most probable identity of the unknown acid?A 500.00 mg vitamin C (MW176.12g/mol) tablet was ground, acidified, and dissolved in H2O to make a 250.0 mL solution. A 50.00 mL aliquot containing vitamin C, KI and starch was analyzed and titrated with 12.31 mL of 0.01042 M KIO3. What is the % (w/w) vitamin C in the tablet? KIO3 + 5 KI + 6 H+ = 3 I2 + 6 K+ + 3 H2O C6H8O6 + I2 = C6H6O6 + 2I- + 2H+ A 67.77 % B 33.89 % C 22.59 % D 3.39 %The thiourea in a 1.455 g sample of organic material was extracted into a dilute sulfuric acid solution and titrated with 37.31 mL of 0.009372 M Hg2+ via reaction: 4(NH2)2CS + Hg2+ →[(NH2)2CS]4 Hg2+ P.S. Answer only the last two letters of the following questions. (Only C and D) a. Is this an example of total analysis technique or concentration technique? Explain. b. Calculate the percent (NH2)2CS ( 76.12 g/mol) in the sample. c. What is classification of the analysis based on the amount of sample and amount of analytes present? Explain. d. If the true value is 10.00%, calculate the absolute and relative error.
- A STOCK SOLUTION containing 0.1581 g/L K2CrO4 was prepared.In order to make the CALIBRATION STANDARD, 5 ml of the STOCK was transferredinto a 50ml volumetric flask and then diluted with an appropriate solvent.Calculate:(a) The ppm of K2CrO4 in the CALIBRATION STANDARD.(b) The molarity of K2CrO4 in the CALIBRATION STANDARD. (c) Calculate the molar absorptivity of K2CrO4 (at 371.0 nm). Assume that Beer's Law isobeyed over this concentration range.At 371.0 nm, this CALIBRATION STANDARD in a cell of path length 1.00 cm gave a %T of 59.752.Direct titration: 10.90 ± 0.02 mL of an unknown KHP solution required 11.72 ± 0.02 mL of 0.1090 ± 0.0006 M NaOH to reach the end point. What is the concentration of KHP in the unknown solution reported with absolute uncertainty? If the unknown solution was prepared by dissolving 5.128 g of the unknown KHP (204.22 g/mol) in 100.00 mL of water, what is the weight percent of KHP in the sample?Sodium carbonate is a reagent that may be used to standardize acids in the same way that you have used KHP in this experiment. In such a standardization it was found that a 0.498-g sample of sodium carbonate required 24.8 mLmL mL of a sulfuric acid solution to reach the end point for the reaction. Na2CO3(aq)+H2SO4(aq)→H2O(l)+CO2(g)+Na2SO4(aq)Na2CO3(aq)+H2SO4(aq)→H2O(l)+CO2(g)+Na2SO4(aq) What is the molarity of the H2SO4H2SO4?
- A mixture of pure BaCO3 and pure Na2CO3 weighs 1.000 g and has the total neutralizing power of 15.37 meq of CaCO3. Calculate the percentage of combined CO2 in the mixture and the weight of Li2CO3 that has the same neutralizing power as 1.000 g of the above mixture. Note: include up to 4 decimal places Please explain each stepA weight of 0.50 g was taken impure container containing sodium carbonate and bicarbonate. Dissolved in water and then crushed with hydrochloric acid (0.1 N), the burette reading game was at the endpoint of phenolphthalein of 10.5 ml and at the end point of the orange methylation point 30.1 ml. The percentage of sodium carbonate was in ................. knowing that the weights are: Na: 23, C: 12, O: 16A pharmacist is conducting an analysis of 2.7 g sodium bicarbonate and titrated with 26.05 mL of 0.9987 N HCl. What is the potency or percent assay of sodium bicarbonate? Did it pass the USP requirement? ROUND-OFF TO 2 DECIMAL PLACES. Answer = _% Disposition (Passed or Failed) = _