A method for the detection of morphine is used to generate a calibration curve in which the assay response (y) is plotted versus morphine concentration (x, in mg/L). This gives a straight line with a slope (m) of 0.241 and a y-intercept (b) of 0.011, where y = mx + b. The slope of this line has a standard deviation of ±0.007, and the standard deviation of the intercept is ±0.006. If the sample from an athlete gives a response of 0.506 ± 0.013 in this method, what is the concentration of morphine in the sample and estimated precision of this concentration?

A method for the detection of morphine is used to generate a calibration curve in which the assay response (y) is plotted versus morphine concentration (x, in mg/L). This gives a straight line with a slope (m) of 0.241 and a y-intercept (b) of 0.011, where y = mx + b. The slope of this line has a standard deviation of ±0.007, and the standard deviation of the intercept is ±0.006. If the sample from an athlete gives a response of 0.506 ± 0.013 in this method, what is the concentration of morphine in the sample and estimated precision of this concentration?

Appl Of Ms Excel In Analytical Chemistry

2nd Edition

ISBN:9781285686691

Author:Crouch

Publisher:Crouch

Chapter4: Least-squares And Calibration Methods

Section: Chapter Questions

Problem 4P

See similar textbooks

Similar questions

Molarity trail 1 0.0366 trail 2 0.0373 trail 3 0.0370 Calculate the standard deviation. Calculate the Relative Standard deviation of molarity to 3 sig figs.
Give the standard deviation of these three molaritys. 0.0366 0.0373 0.0370
A quantitative analysis for an analyte gives a mean concentration of 12.6 ppm. The standard deviation due to the method, sm, is found to be 1.1 ppm, and that due to sampling, ss, is 2.1 ppm. By how much does the overall variance change if sm is improved by 10% and ss is improved by 15%?
Individually weigh each of the nine nickels used in part 2b. Then calculate the average,average deviation, and standard deviation of the nine samples. The mass of a U. S. nickel,when minted, is 5.000 g. What is the percent error between your average and the U. S. Mintvalue? Pay close attention to your significant figures when doing these calculations. Sample Mass (g) Average Mass ____________ gNo.1 _5.029 ______ Average Deviation ____________ g2 _5.010 ______ Standard Deviation ____________ g3 _4.983 ______ Percent Error ____________ %4 _5.036 ______5 _4.989 ______6 _5.026 ______7 _5.028 ______8 _4.980 ______9 _4.952 ______ im having issues with average deviation and standard deviation
A volumetric calcium analysis on samples of the blood serum of a patient believed to be suffering from a hyperparathyroid condition produced the following data: mmol Ca/L = 3.10, 3.08, 3.28, 3.15, 3.26, 3.12, 3.14, 3.18, 3.25, 3.11, 2.95. Calculate: Mean Standard deviation Coefficient of variation What is the 95% confidence interval for the mean of the data, assuming no prior information about the precision of the analysis? Apply the Q test to the following data sets to determine whether the outlying result should be retained or rejected at the 95% confidence level. ( work on the first measurements according to your case)
Estimate the absolute standard deviation (or uncertainty) for the results of the following calculations. Round each result so that it contains only significant digits. The numbers in parentheses are absolute standard deviations. Show your solution and express the final answer and its corresponding uncertainty. a) y= 2.998(±0.002) - 3.98 (±0.15) + 9.035 (±0.002) = 8.0531 b) y= 39.2(±0.3) x 3.054 (±0.022) x 10^ -2 = 1.197 c) y= [198(±6) - 89 (±3)] / 1335 (±2) + 64 (±7)] = 7.791 x 10^-2
Which of the statements below are TRUE regarding the mean and standard deviation? I. As the number of measurements increases, x̄ approaches μ if there is no random error.II. The square of the standard deviation is the average deviation.III. The mean is the center of the Gaussian distribution.IV. The standard deviation measures the width of the Gaussian distribution.
1. A student performed this experiment and obtained the following concentration values: 0.02813 M, 0.02802, and 0.02788 M a. what is the mean concentration? b. what is the standard deviation of these results? 3. how would the following errors affect the concentration of Cl- obtained in question 2b? give your reasoning in each case. a. the student read the molarity of AgNo3 as 0.02104M instead of 0.02014M b. the student was past the endpoint of titration when he took the final buret reading.
The gold content of an ore is being measured. The results of these analyses are: Content (ppt) 20.065 19.999 21.054 20.533 20.088 20.112 What is the average value, standard deviation and confidence interval for this set of data?Show each step of the calculation. Using your results calculate the %accuracy and %precision (relative standard deviation) if the true value is 20.045%.
Normality of a solution was determined by five different titrations. The results were 9.5 mL, 8.5 mL, 9.1 mL, 9.3 mL, and 9.1 mL. Calculate the mean, median and standard deviation of this data
What are the differences between systematic and random errors and how do they effect accuracy and precision? In what circumstances would you use standard addition (versus a normal calibration curve) to determine the amount of an analyte in a sample? A urine sample, containing analyte Z is analysed by the standard addition method where 5 mL of the original sample was mixed with increasing amounts of a Z standard and each solution diluted to a volume of 50 mL prior to analysis. A plot of the final concentration of the standard in each of the 50 mL samples (x axis) versus The measured signal from the analysis of each 50 mL sample (on y axis) produced a straight line with the general equation: y = 44.72x + 4.06 what was the final concentration of Z in the 50 mL standard addition sample? what was the initial concentration of Z in the original urine sample?
An excess of 0.34 mg Pb is obtained from an assay test determined in an analysis. What is the percent relative error in ppt if the mass of the sample is 550 g?