A mixture of 50 mol % benzene and 50 mol % toluene is distilled under exactly the same conditions as in Part a. Using Figure 5.1, determine the distillation temperature and the percentage composition of the first few drops of distillate.

EBK A SMALL SCALE APPROACH TO ORGANIC L
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ISBN:9781305446021
Author:Lampman
Publisher:Lampman
Chapter84: Fractional Distillation, Azeotropes
Section: Chapter Questions
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b. A mixture of 50 mol % benzene and 50 mol % toluene is distilled under exactly the same
conditions as in Part a. Using Figure 5.1, determine the distillation temperature and the
percentage composition of the first few drops of distillate.
c. The normal boiling points of n-propylcyclohexane and n-propylbenzene are 156 °C and
159 °C, respectively. Compare the distillation results in Parts a and b. Which of the two
mixtures would require the more efficient fractional distillation column for separation of
the components? Why?
Transcribed Image Text:b. A mixture of 50 mol % benzene and 50 mol % toluene is distilled under exactly the same conditions as in Part a. Using Figure 5.1, determine the distillation temperature and the percentage composition of the first few drops of distillate. c. The normal boiling points of n-propylcyclohexane and n-propylbenzene are 156 °C and 159 °C, respectively. Compare the distillation results in Parts a and b. Which of the two mixtures would require the more efficient fractional distillation column for separation of the components? Why?
icher in the more volatile component
quilibrium. This phenomenon provides the basis of fractional distillation.
Vapor
Line
Liquid
Line
D
E
mol % Toluene
20
40
60
80
100
mol % Benzene 100
80
60
40
20
Composition
Figure 5.1. Temperature-composition diagram for binary mixture of benzene and toluene.
Temperature (C)
Transcribed Image Text:icher in the more volatile component quilibrium. This phenomenon provides the basis of fractional distillation. Vapor Line Liquid Line D E mol % Toluene 20 40 60 80 100 mol % Benzene 100 80 60 40 20 Composition Figure 5.1. Temperature-composition diagram for binary mixture of benzene and toluene. Temperature (C)
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