A Pb-Sn alloy contains 10% primary a and 90% eutectic microconstituent immediately after the eutectic reaction has been completed.400OL300SolidusTemperature (°C)200Solidus19183°-Solvusα + ßPb206040Weight percent tinDetermine the composition (in wt% Sn) of the alloy.%100Liquidusαa + L61.9LiquidusB+L97.5Solvus80-BSn

A Pb-Sn alloy contains 10% primary ἀ and 90% eutectic micro constituent immediately after the…

A Pb-Sn alloy contains 10% primary a and 90% eutectic microconstituent immediately after the eutectic reaction has been completed. 400 L 300 Temperature (°C) Solidus 19 -Solvus 100- a + ß I 1 % 20 40 60 Weight percent tin Determine the composition (in wt% Sn) of the alloy. 200 Liquidus a + L 1 183° 61.9 Liquidus 1 B+L 97.5 Solvus 1 80 -B Sn O Solidus

A Pb-Sn alloy contains 10% primary a and 90% eutectic microconstituent immediately after the eutectic reaction has been completed. 400 L 300 Temperature (°C) Solidus 19 -Solvus 100- a + ß I 1 % 20 40 60 Weight percent tin Determine the composition (in wt% Sn) of the alloy. 200 Liquidus a + L 1 183° 61.9 Liquidus 1 B+L 97.5 Solvus 1 80 -B Sn O Solidus

Principles of Instrumental Analysis

7th Edition

ISBN:9781305577213

Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch

Publisher:Douglas A. Skoog, F. James Holler, Stanley R. Crouch

Chapter23: Potentiometry

Section: Chapter Questions

Problem 23.12QAP: What arc the advantages of microfabricated ISEs? Describe typical applications of this type of...

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6.1) At the composition of 0.77% by weight C, identify the phase(s) presentat 950 degrees C 6.2) When the specimen is at 950 degrees C, what is the maximum C composition at which a single phase Austenite is stable?6.3) If we slowly cool a Fe-C alloy with 0.77% by weight C, austenitized at950 degrees C, to just below the eutectoid temperature of 727 degrees C, give the weight percentage and composition of the phases present based on the phase diagram given above6.4) If we cool very quickly a Fe-C alloy with 0.77% by weight C,austenitized at 950 degrees C, to room temperature, give the weight percentage and composition of the phase(s) present
In a system ABC, a ternary alloy with composition of 30 wt. % B and 30 wt. % C consists at a particular temperature of three phases of equilibrium compositions as follows:Liquid phase: 50 % A, 40 % B, 10 % Calfa solid solution: 85 % A, 10 % B, 5 % Cbeta solid solution: 10 % A, 20 % B, 70 % Ca. Plot the composition of the alloy.b. Calculate the proportion by weight of liquid,  and  present in this alloy.c. For the same temperature, find the composition of the alloy which will consist of equal proportion of  and  phases of the compositions stated above, but with no liquid phase.
Suppose you have a soil that is made up of 10% organic matter with CEC = 200 cmol/kg, 40% kaolinitewith CEC = 10 cmol/kg, and 50% vermiculite with CEC = 100 cmol/kg.1- Calculate the overall CEC of the soil by taking a weighted average of the three soil components.2- What percentage of the overall CEC is contributed by the organic matter? How does that numbercompare to the 10% of the soil itself that is organic?
Microstructure of a steel contain 100% coarse pearlite it carbon content is reported to be 0.65% is it possible? And why ?
A chemist received different mixtures for analysis with the statement that they contained NaOH, NaHCO3, Na2CO3, or compatible mixtures of these substances, together with inert material. From the data given, identify the respective materials, and calculate the percentage of each component. 1.000g samples and 0.2500N HCl were used in all cases. (A) For Sample W: With PP, 24.32ml was used. A duplicate sample required 48.64ml with MO. (B). For Sample X: The addition of PP caused no color change. With MO, 38.47ml of the acid was required. (C). For Sample Y: To cause a color change in the cold with PP, 15.29ml of the acid was necessary, and an additional 33.19ml was required for complete neutralization. (D) For Sample Z: The sample was titrated with acid until the pink of PP disappeared; this process required 39.96ml. On adding an excess of the acid, boiling, and titrating back with alkali, it was found that the alkali was exactly equivalent to the excess acid added.
10.11/ A 1.5-kg specimen of a 90 wt% Pb-10 wt% Sn alloy is heated to 250°C (480°F), at which temperature it is entirely an a-phase solid solution . The alloy is to be melted to the extent that 50% of the speci- men is liquid, the remainder being the a phase. This may be accomplished either by heating the alloy or changing its composi- tion while holding the temperature con- stant. (a) To what temperature must the speci- men be heated? (b) How much tin must be added to the 1.5-kg specimen at 250°C to achieve this state? 10.15) A magnesium-lead alloy of mass 5.5 ka consists of a solid a phase that has a compo- sition that is just slightly below the solubility limit at 200°C (390°F). (a) What mass of lead is in the alloy? (b) If the alloy is heated to 350°C (660°F). how much more lead may be dissolved in the a phase without exceeding the solubility limit of this phase? 10.27 A hypothetical A-B alloy of composition 55 wt% B-45 wt% A at some temperature is found to consist of mass…
A 90 wt% Ag-10 wt% Cu alloy is heated to a temperature within the β + liquid phase region. If the composition of the liquid phase is 85 wt% Ag, determine:(i) The temperature of the alloy(ii) The composition of the β phase(iii) The mass fractions of both phases
The %purity of a powdered crude sample of Na2CO3 containing only inert impurities is to be determined by reacting 225.0 mg of the crude sample to 10.0 mL of 3.00 M HCl solution, and bubbling the resulting CO2(g) product in water that is at exactly 29 °C. After the reaction has completed, the level of the liquid inside the eudiometer rests 4.30 cm above the water level in the beaker. The graduation on the eudiometer indicates that the trapped gas is 44.37 mL. The experiment was done under a barometric pressure of 755.2 torr. a. How many moles of CO2 were collected? b. What is the percent purity of the sample? Round off to the nearest whole number
The %purity of a powdered crude sample of Na2CO3 containing only inert impurities is to be determined by reacting 225.0 mg of the crude sample to 10.0 mL of 3.00 M HCl solution, and bubbling the resulting CO2(g) product in water that is at exactly 29 °C. After the reaction has completed, the level of the liquid inside the eudiometer rests 4.30 cm above the water level in the beaker. The graduation on the eudiometer indicates that the trapped gas is 44.37 mL. The experiment was done under a barometric pressure of 755.2 torr. What CASE does this experiment satisfy?
For a Copper-Nickel (Cu-Ni) alloy of composition 25 wt % Ni and 75 wt % Cu at 1200 OC (Point B), refer to the phase diagram provided in Figure 2 and answer the following. (i) What is composition of liquid phase? (ii) What is composition of solid phase? (iii) What fraction of the system is liquid for a 25% Ni alloy at 1250 OC? (iv) What fraction of the system is solid for a 25% Ni alloy at 1250 OC?
Given the solubility of ferrihydrite (Fe(OH)3) and goethite (FeOOH), with dissolution reactions shown below: [1] Fe(OH)3 3 H+ à Fe3+ + 3 H2O Ksp = 8.4 x 10^4 ∆ Gr0 = -28 KJ/mol Solubility of Fe(OH3) = 7.468 [2] FeOOH + 3 H+ à Fe3+ + 2 H2O Ksp = 8.8 x 10^-2 ∆ Gr0 = 6 KJ/mol Solubility of FeOOH = 0.353 QUESTION: [A] How much Fe3+ from ferrihydrite would dissolve at pH 2 ? [B] How much Fe3+ from ferrihydrite would dissolve at pH 7 ? [C] How much Fe3+ from goethite would dissolve at pH 2 ? [D] How much Fe3+ from goethite would dissolve at pH 7 ?
1) The ratio strength of a 10mL vial of neostigmine methylsulfate injection USP is 1:1500. Calculate the amount of neostigmine methylsulfate in milligrams contained in the 10mL vial. (Round to the whole number).