A voltaic cell is constructed that uses the following half-cellreactions:Cu+(aq) + e- ----->Cu(s)I2(s) + 2 e- ----->2 I-(aq)The cell is operated at 298 K with [Cu+] = 0.25 M and[I-] = 0.035 M. (a) Determine E for the cell at these concentrations.(b) Which electrode is the anode of the cell?(c) Is the answer to part (b) the same as it would be if the cellwere operated under standard conditions? (d) If [Cu+] wereequal to 0.15 M, at what concentration of I- would the cellhave zero potential?

Chemistry: Principles and Reactions
8th Edition
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:William L. Masterton, Cecile N. Hurley
Chapter17: Electrochemistry
Section: Chapter Questions
Problem 105QAP: Consider a voltaic cell in which the following reaction occurs. Zn(s)+Sn2+(aq)Zn2+(aq)+Sn(s) (a)...
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A voltaic cell is constructed that uses the following half-cell
reactions:
Cu+(aq) + e- ----->Cu(s)
I2(s) + 2 e- ----->2 I-(aq)
The cell is operated at 298 K with [Cu+] = 0.25 M and
[I-] = 0.035 M. (a) Determine E for the cell at these concentrations.
(b) Which electrode is the anode of the cell?
(c) Is the answer to part (b) the same as it would be if the cell
were operated under standard conditions? (d) If [Cu+] were
equal to 0.15 M, at what concentration of I- would the cell
have zero potential?

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