Chemistry for Engineering Students
3rd Edition
ISBN:9781285199023
Author:Lawrence S. Brown, Tom Holme
Publisher:Lawrence S. Brown, Tom Holme
Chapter5: Gases
Section: Chapter Questions
Problem 5.23PAE
Related questions
Question
Identify each compound below from its molecular formula and its 13C NMR spectrum.
Expert Solution
Step 1
The following rules should be followed to deduce the structure of unknown compound from the 13-C NMR data.
1) Check the number of signals in the spectrum which gives information regarding number of non-equivalent carbons in the molecule.
2) Identify the easily predictable signals in the spectrum, from which derive the possible fragments.
3) Subtract the chemical formula of all the derived fragments from the given molecular formula to know the remaining fragment.
4) At last, assemble all the fragments to get the structure of molecule which satisfies the given data.
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