The table shows signals from an electrochemical detector for the measurement of mcthane (CH4). CH(%vol) Sign (mV) 0. 0.062 0.11 0.245 0.486 0.971 1.921 1671.9 9.1 47.5 95.6 193.8 387.5 812.5 a) Subtract the blank value (9.1) from all other signal values to obtain the corrected signals. Perform the calibration curve by plotting corrected signal (y) vs CH4 (% vol) (x) in Microsoft excel. Present the graph and the equation of the line given by this program. b) Calculate the uncertainty in y according to the following equation, show the replaced values and the result rounded to 2 significant figures: E(d) Sy = n-2 c) Calculate the uncertainty in b according to the following equation, show the replaced values and the result rounded to 2 significant figures: Sp = Sy %3D D

Principles of Modern Chemistry
8th Edition
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Chapter20: Molecular Spectroscopy And Photochemistry
Section: Chapter Questions
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The table shows signals from an electrochemical detector for the measurement of methane (CH).
CH(%vol) 0
Sign (mV)
0.062
0.11
0.245
0.486
0.971
1.921
9.1
47.5
95.6
193.8
387.5
812.5
1671.9
a) Subtract the blank value (9.1) from all other signal values to obtain the corrected signals.
Perform the calibration curve by plotting corrected signal (y) vs CH4 (% vol) (x) in Microsoft
excel. Present the graph and the equation of the line given by this
program.
b) Calculate the uncertainty in y according to the following equation, show the replaced values
and the result rounded to 2 significant figures:
E(d)
Sy
n-2
c) Calculate the uncertainty in b according to the following equation, show the replaced values
and the result rounded to 2 significant figures:
Sp = Sy
d) Calculate the uncertainty in m according to the following equation, show the replaced values and the
result rounded to 2 significant figuresa
Sm = Sy
%3D
e) Present the equation of the line as follows:
y(ts,) = m(±Sm)x+b(±S»)
Transcribed Image Text:The table shows signals from an electrochemical detector for the measurement of methane (CH). CH(%vol) 0 Sign (mV) 0.062 0.11 0.245 0.486 0.971 1.921 9.1 47.5 95.6 193.8 387.5 812.5 1671.9 a) Subtract the blank value (9.1) from all other signal values to obtain the corrected signals. Perform the calibration curve by plotting corrected signal (y) vs CH4 (% vol) (x) in Microsoft excel. Present the graph and the equation of the line given by this program. b) Calculate the uncertainty in y according to the following equation, show the replaced values and the result rounded to 2 significant figures: E(d) Sy n-2 c) Calculate the uncertainty in b according to the following equation, show the replaced values and the result rounded to 2 significant figures: Sp = Sy d) Calculate the uncertainty in m according to the following equation, show the replaced values and the result rounded to 2 significant figuresa Sm = Sy %3D e) Present the equation of the line as follows: y(ts,) = m(±Sm)x+b(±S»)
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