Bond-line FormulaIUPAC Nameh.BrCIi.Brj.

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Organic Chemistry: A Guided Inquiry

2nd Edition

ISBN:9780618974122

Author:Andrei Straumanis

Publisher:Andrei Straumanis

Chapter2: Lewis Structures

Section: Chapter Questions

Problem 8CTQ

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Similar questions

On the left side of Figure 3.6, label the areas shown with a dotted line where... one bond can form. one bond can form.
Consider the following flat drawing of methane (CH4) . a. What is HCH bond angle implied by this drawing if you assume it is flat? b. Are the electron domains of this flat CH4 spread out as much as possible? c. Use model materials to make a model of CH4 (methane). If you assembled it correctly, thefour bonds (bonding electron domains) of your model will be 109.5° apart. d. In which representation, the drawing above or the model in your hand (circle one) are theH’s of CH4 more spread out around the central carbon? e. Confirm that your model looks like the following drawing. The wedgebond represents a bond coming out of the page, and the dash bondrepresents a bond going into the page f. You will often see methane drawn as if it were flat (like on the previous page). Why is thismisleading, and what is left to the viewer’s imagination when looking at such a drawing?
( plz explaing with clear diagram and bond angle )
I waasnt sure about the sigma and pi bonds sentence. Would they not be broken because they are present in all bonds, no matter the type of IMF?
For each of the following molecules, complete the Lewis structure and use the VSEPR model to determine the bond angles around each central atom. Note that the drawings are only skeleton structures and may depict the angles incorrectly.
Use Figs. 4-54 and 4-55 to answer the following questions. a. Would the bonding molecular orbital in HF place greater electron density near the H or the F atom? Why? b. Would the bonding molecular orbital have greater fluorine 2p character, greater hydrogen 1s character, or an equal contribution from both? Why? c. Answer the previous two questions for the antibonding molecular orbital in HF.
Compare Figs. 4-47 and 4-49. Why are they different? Because B2 is known to be paramagnetic, the 2p and 2p molecular orbitals must be switched from the first prediction. What is the rationale for this? Why might one expect the 2p to be lower in energy than the 2p? Why cant we use diatomic oxygen to help us decide whether the 2p, or 2p, is lower in energy?
Which atomic orbitals overlap to form the bonds in ClF?
A student who missed this class needs to know how to predict the bond angles and shape of amolecule from looking at its bond-line representation. Write a concise but complete explanationfor this student.
A paper published in the research Journal Science in 2007 (S. Vallina and R. Simo, Science, Vol. 315, p. 506, January 26, 2007) reported studies of dimethylsulfide (DMS), an important green-house gas that is released by marine phytoplankton. This gas represents the largest natural source of atmospheric sulfur and a major precursor of hygroscopic (i.e., cloud-forming) particles in clean air over the remote oceans, thereby acting to reduce the amount of solar radiation that crosses the atmosphere and is absorbed by the ocean. (a) Sketch the Lewis structure of dimethylsulfide, CH3SCH3, and list the bond angles in the molecule. (b) Use electronegativities to decide where the positive and negative charges lie in the molecule. Is the molecule polar? (c) The mean seawater concentration of DMS in the ocean in the region between 15 north latitude and 15 south latitude is 2.7 nM (nanomolar). How many molecules of DMS are present in 1.0 m3 of seawater?
A student draws the picture of ammonia (NH3) in the box below, left, and predicts it will be a flatmolecule with HNH bond angles of exactly 120°. Unfortunately, the student left something out. a. What did the student omit from his drawing? b. What is the actual HNH bond angle of ammonia (based on the draw g above, right)? c. Explain why water, ammonia, and methane (shown below) all have about the same bondangles (close to 109.5°) even though they have different numbers of bonds.
Use VSEPR theory to predict the shape of this molecule (POC13) and indicate any deviation from the bond angle(s) expected from a regular arrangement of repulsion axes. Show all the steps took to arrive at answer 4 to five sentences

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Bond-line Formula IUPAC Name h. Br i. Br