Calculate the CFSE of the complex. Determine the hybridization of the metal central in the complex. Calculate the spin-only magnetic moment of the metal central in the complex.

Q: [Ni (NH3) 6] C12 Explain the hybridization, geometry and magnetic property of the complex structure.

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Q: Draw the molecular orbital diagram of the -complex ion [Fe(H2O)6]2+, also arrange the electronic…

A: [Fe(H2O)6]2+ consists of 6 H2O ligands and an oxidation state of +2 which means Fe consists of 6…

Q: Consider the d' electron configuration of a free ion: a) Calculate the spin multiplicity

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Q: Which cation is mostly likely to form a complex with SCN¯ bonded through the sulfur atom? Nj2+ A]3+…

A: From the concept of HSAB principle we get the answer

Q: Draw combinations of orbitals by using all three p orbitals of atom A and all five d orbitals of…

A: The region in the three-dimensional space of an atom and it has a greater probability of finding an…

Q: Draw the orbital splitting diagram for the complex: [Rh(en)3]3+. Rh° : [Kr] 5s²4d7

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Q: Draw the hybridization for the metal centre of the complex below. You need to determine the geometry…

A: Hybridization is the process of mixing up of atomic orbitals to give new orbitals, hybrid orbitals.…

Q: Write the state of hybridisation, the shape and the magnetic behaviour of the following complex…

A: (i) [Cr(NH3)4Cl2]Cl: Hybradisation of [Cr(NH3)4Cl2]Cl is d2sp3 Geometry of [Cr(NH3)4Cl2]Cl is…

Q: Draw a molecular orbital diagram to show that CH3 molecule is a ơ-donor ligand.

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Q: For an octahedral complex BA6, please determine the point groups of the following structures derived…

A: "Since there are multiple sub-parts in this question and it is not mentioned that which one has to…

Q: Square planar complexes are often asso with:

A: Square planar complexes are dsp2 hybridised .

Q: Determine the type of hybrid orbitals and the spatial structure of the following two complexes. A)…

A: A) Atomic number of Fe is 26. Electronic Configuration of Fe is [Ar]3d64s2 Electronic Configuration…

Q: A coordination complex is formed between a (divalent) zinc cation and four cyanide anions. Cyanide…

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Q: Let’s consider octahedral Sc3+ and Ti3+ complexes.  How many d electrons will each have? Sc3+: 0;…

A: How many d electrons will each have? Sc3+ and Ti3+

Q: What determine whether a molecule or ion complex is chiral? How would you differentiate between…

A: A chiral is an object that is not identically super-imposable with a mirror image of itself. An…

Q: Which of the following orders is correct for Tolman cone angles for PR3 ligands? а. РМез > РET3 b.…

A: Tolman Cone angle          → Depends on the basis of steric size . Layer the size layer is the…

Q: How can I explain the complex trans - [CoBr2(en)2] by the crystalline field theory

A: This is an octahedral complex. The oxidation state of Co in this complex is +2. Co+2 = 1s2 2s2 2p6…

Q: Determine the number of isomers, and draw the structures and any enantiomer pairs, for the following…

A: The isomers can be calculated by simplifying the structure of the complex by changing the trans…

Q: <p>Draw a crystal field splitting diagram for a trigonal planar complex ion. Assume the plane…

A: The d orbital electrons of a transition metal split into high and low energy levels in ligand field.…

Q: Draw a molecular orbital diagram to show that CH3 molecule is a o-donor ligand.

A: Molecular orbital is termed as when the atomic orbital of atom overlap, they drop their identity and…

Q: Calculate the Ligand-field stabilization energies (LFSE) for octahedral compounds which contain the…

A: The high spin complexes contain the unpaired electrons whereas the low spin complexes contain the…

Q: Draw a molecular orbital diagram to show that CH3¯ molecule is a -donor ligand.

A: A molecular orbital diagram, or MO diagram, is a qualitative descriptive tool explaining chemical…

Q: For the complex [Pt(NH3)2(H2O)2](NO3)2 draw the d-orbital splitting diagram for platinum (Pt) (high…

A: Pt forms square planar complex.

Q: 3. Square planar Ir complexes have been widely studied in organometallic catalysis. Provided the…

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Q: Explain the hybrid type and geometric structure of the K3 [Cr (C204) 3] .3H2O complex with VBT.

A: oxidation number of Cr is +3  in this compound .

Q: What can you determine about the structure of a coordination complex by measuring its conductance in…

A: The conductance of the coordination compound is used to predict the no. of ions present in the…

Q: Hexaamminenickel 2 chloride ( [Ni(NH3)6]Cl2 )Explain the hybridization, geometry, and magnetic…

A: [Ni(NH3)6]Cl2 ; In this complex , Ni(28) is present as Ni+2  ion .Ni has valence shell configuration…

Q: how can I explain the complex trans – [CoBr2(en)2] by valence bond theory

A: VBT is the valence bond theory which describes the bonding of the complex in the coordination…

Q: Determine the electronic configuration (in the form t2g "eg or emt2" , as appropriate) and the…

A: In transition metal octahedral complexes, in the presence of ligand field d orbitals split into two…

Q: Calculate the gas phase or free ion term for a d8 transition metal ion and the ground and excited…

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Q: [Fe(H2O)6]²+

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Q: hy do ligands cause the d orbitals of a transition metal ion to cease being degenerate? A. New…

A: Interpretation: We have to tell why do ligands cause the d orbitals of a transition metal ion to…

Q: Write the state of hybridization, the shape and the magnetic behaviour of the following complex…

A: In order to find out the hybridization following steps are followed: The oxidation state of metal is…

Q: For each of the following ions, draw diagrams (on a piece of paper), like the one to the right…

A: Applying concept of electronic configuration of ions .

Q: Calculate the Ligand-field stabilization energies (LFSE) for tetrahedral compounds which contain the…

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Q: In a trigonal bipyramidal geometry, the electron pairs from the ligands come in along the z-axis…

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Q: ÇO,Me MeO2C, .CO2ME N' Mn N' MeO2C `CO2ME CO2ME

A: what's the hybridisation of the metal in the complex ?

Q: The value of ∆ for the [CrF6]3- complex is 182 kJ/mol. Calculate the expected wavelength of the…

A: CFSE: Crystal field stabilization energy It is defined as the energy of the electron configuration…

Q: calculate the CFSE using Crsytal Field Theory. Compounds: Al(acac)3 , Cr(acac); , Cu(acac)2 a) Name…

A: Valence Bond theory describes covalent bond formation. According to this theory electrons occupy…

Q: (1I) According to the valence bond theory (VBT) answer the following regarding to [NicIj? complex.…

A: Nickel has 28 Electrons, electronic configuration of 1s2,2s2,2p6,3s2,3p6,4s2, 3d8. While Ni2+ ion…

Q: Which hybridization(s) is/are suitable to form a metal complex? (You can select more than one option…

A: Hybridization which are suitable for metal complex formation are sp, sp2, sp3 , dsp3 . Let's see by…

Q: Which d orbital on M (center metal) is capable of having a bonding interaction with the ligand group…

A: dx2-y2  is capable of forming bonding interaction with the ligands because ligands approach or…

Q: The cyanide anion CNis a very good ligand towards metal ions. Represent the Lewis formula of the…

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Q: Draw the hybridization for the metal centre of the complex below

A: According to Valence bond theory: Electrons in a molecule occupy atomic orbitals rather than…

Q: What are the special features of the frontier orbitals of the CO molecule? How do they affect the…

A: Molecular orbital depictes that carbon atom has more contribution in the HOMO of CO molecule. So,…

Q: What are the characteristics of outer orbital complexes for octahedral complexes 1_hybridization is…

A: When the inner d orbital is used for hybridization then it is inner orbital complex . But when it is…

Q: For a given metal ion and set of ligands, is the crystal-field splitting energy larger for a…

A: In tetrahedral geometry, the central metal atom is attached to four surrounding ligands. While in…

Coordination Chemistry

It is a part of chemistry, in which the study of compounds that have central atoms surrounded by molecules or ions, known as ligand, is known as coordination chemistry.