Calculate the energies of the 4 conformers below:

Organic Chemistry
9th Edition
ISBN:9781305080485
Author:John E. McMurry
Publisher:John E. McMurry
Chapter3: Organic Compounds: Alkanes And Their Stereochemistry
Section3.SE: Something Extra
Problem 47AP: Draw the most stable conformation of 1,4-dichlorobutane, using wedges and dashes to represent bonds...
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Question 29
Calculate the energies of the 4 conformers below:
Me
H Me
Me
H.
H Me
Me
H.
H.
-Me
Me
H.
Me
Me
H
Mé
Ме
H.
Me
Erel
Erel =
Erel=
Erel
Me-Me Gauche: 3.8 kJ/mol; eclispsed H-H: 4 kJ/mol; eclipsed Me-H: 6.0 kJ/mol; eclipsed Me-Me: 11 kJ/mol
О 83B 23;B 0%;B 18
O 22; 18.8; 7.6; 18
O 7.6; 21; 3.8; 18
О 19.6;B 24.8;B 7.8;B 21.8
Transcribed Image Text:Question 29 Calculate the energies of the 4 conformers below: Me H Me Me H. H Me Me H. H. -Me Me H. Me Me H Mé Ме H. Me Erel Erel = Erel= Erel Me-Me Gauche: 3.8 kJ/mol; eclispsed H-H: 4 kJ/mol; eclipsed Me-H: 6.0 kJ/mol; eclipsed Me-Me: 11 kJ/mol О 83B 23;B 0%;B 18 O 22; 18.8; 7.6; 18 O 7.6; 21; 3.8; 18 О 19.6;B 24.8;B 7.8;B 21.8
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