Calculate the wavelength of photons absorbed in molecules with 5, 7, 9, and 11 double bonds (DB) when electrons transition from the HOMÓ (level n) to the next level above the LUMO (level n+2) Calculate the wavelengths of photons absorbed in molecules with 5, 7, 9, and 11 double bonds (DE) when electrons transition from the HOMO (level n) to the next level above the LUMO (level n+2). n-5 LUMO nn4 HOMO n=3 n=2 (A) Wavelength for 5 DB nm ) Wavelength for 7 DB o Wavelength for 9 DB- nm id) Wavelength for 11 DB Plot a graph of absorption wavelength vs the number of double bonds. What type of graph is this? Opower law Cexponential inear Cparabolic

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Chapter8: Thermochemistry
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Calculate the wavelength of photons
absorbed in molecules with 5, 7, 9, and 11
double bonds (DB) when electrons transition
from the HOMÓ (level n) to the next level
above the LUMO (level n+2)
Calculate the wavelengths of photons absorbed in molecules with 5, 7, 9, and 11 double bonds (DB) when electrons transition from the
HOMO (level n) to the next level above the LUMO (level n+2).
n=6
n-5 LUMO
n-4 HOMO
n=3
n=2
n=1
(a) Wavelength for 5 DB
nm
(b) Wavelength for 7 DB
nm
() Wavelength for 9 DB-
nm
(d) Wavelength for 11 DB=
nm
Plot a graph of absorption wavelength vs. the number of double bonds. What type of graph is this?
Opower law
Cexponential
linear
Oparabolic
Transcribed Image Text:Calculate the wavelength of photons absorbed in molecules with 5, 7, 9, and 11 double bonds (DB) when electrons transition from the HOMÓ (level n) to the next level above the LUMO (level n+2) Calculate the wavelengths of photons absorbed in molecules with 5, 7, 9, and 11 double bonds (DB) when electrons transition from the HOMO (level n) to the next level above the LUMO (level n+2). n=6 n-5 LUMO n-4 HOMO n=3 n=2 n=1 (a) Wavelength for 5 DB nm (b) Wavelength for 7 DB nm () Wavelength for 9 DB- nm (d) Wavelength for 11 DB= nm Plot a graph of absorption wavelength vs. the number of double bonds. What type of graph is this? Opower law Cexponential linear Oparabolic
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