Calculating the pH at equivalence of a titrationA chemist titrates 230.0 mL of a 0.3847 M hydrocyanic acid (HCN) solution with 0.2111 M NAOH solution at 25 °C. Calculate the pH at equivalence.The p K, of hydrocyanic acid is 9.21.Round your answer to 2 decimal places.Note for advanced students: you may assume the total volume of the solution equals the initial volume plus the volume of NaOH solution added.olopH =Ar

At equivalence point the number of moles (nNaOH) of NaOH is equal to the number of moles (nHCN) of…

Answered: Calculating the pH at equivalence of a…

Chemistry: Principles and Practice

3rd Edition

ISBN:9780534420123

Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer

Publisher:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer

Chapter16: Reactions Between Acids And Bases

Section: Chapter Questions

Problem 16.58QE

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Similar questions

Sketch a titration curve for the titration of potassium hydroxide with HCl, both 0.100 M. Identify three regions in which a particular chemical species or system dominates the acid-base equilibria.
Ka for formic acid is 1.7 104 at 25C. A buffer is made by mixing 529 mL of 0.465 M formic acid, HCHO2, and 494 mL of 0.524 M sodium formate, NaCHO2. Calculate the pH of this solution at 25C after 110 mL of 0.152 M HCl has been added to this buffer.
Calculate the pH of solutions that are 0.25 M formic acid and 0.40 M sodium formate. 0.50 M benzoic acid and 0.15 M sodium benzoate.
A student intends to titrate a solution of a weak monoprotic acid with a sodium hydroxide solution but reverses the two solutions and places the weak acid solution in the buret. After 23.75 mL of the weak acid solution has been added to 50.0 mL of the 0.100 M NaOH solution, the pH of the resulting solution is 10.50. Calculate the original concentration of the solution of weak acid.
Ammonia gas is bubbled into 275 mL of water to make an aqueous solution of ammonia. To prepare a buffer with a pH of 9.56, 15.0 g of NH4Cl are added. How many liters of NH3; at 25C and 0.981 atm should be used to prepare the buffer? Assume no volume changes and ignore the vapor pressure of water.
A solution of weak base is titrated to the equivalence point with a strong acid. Which one of the following statements is most likely to be correct? a The pH of the solution at the equivalence point is 7.0. b The pH of the solution is greater than 13.0. c The pH of the solution is less than 2.0. d The pH of the solution is between 2.0 and 7.0. e The pH of the solution is between 7.0 and 13.0. The reason that best supports my choosing the answer above is a Whenever a solution is titrated with a strong acid, the solution will be very acidic. b Because the solution contains a weak base and the acid (titrant) is used up at the equivalence point, the solution will be basic. c Because the solution contains the conjugate acid of the weak base at the equivalence point, the solution will be acidic.
When 40.00 mL of a weak monoprotic acid solution is titrated with 0.100-M NaOH, the equivalence point is reached when 35.00 mL base has been added. After 20.00 mL NaOH solution has been added, the titration mixture has a pH of 5.75. Calculate the ionization constant of the acid.
A 25.0-mL sample of hydroxylamine is titrated to the equivalence point with 35.8 mL of 0.150 M HCl. a What was the concentration of the original hydroxylamine solution? b What is the pH at the equivalence point? c Which indicators, bromphenol blue, methyl red, or phenolphthalein, should be used to detect the end point of the titration? Why?
For the titration of 50.0 mL of 0.150 M ethylamine. C2H5NH2, with 0.100 M HCl, find the pH at each of the following points, and then use that information to sketch the titration curve and decide on an appropriate indicator. (a) At the beginning, before HCl is added (b) At the halfway point in the titration (c) When 75% of the required acid has been added (d) At the equivalence point (e) When 10.0 mL more HCl has been added than is required (f) Sketch the titration curve. (g) Suggest an appropriate indicator for this titration.
A 0.025 M solution of an unknown organic acid has a pH of 3.23. 2.1 By means of a full calculation, determine the value of the ionisation constant of the conjugatebase of this acid..- You may use “HA” to denote the formula of the acid.- You may make certain assumptions to simplify your calculations2.2 A certain amount of the sodium salt of the conjugate base of the acid was added to the system.Will the pH of the resulting solution increase or decrease, compared to the original given value? Explain your answer in a short sentence or two.
1. You are taking samples at a contaminated mine site from a carbonate aquifer to determine the concentration of dissolved lead in the sample. To preserve the sample, you acidify it to pH 5. How much HCl, in equivalents/L, must be added to this sample to make it pH 5 if the total carbonate concentration is 102 M and the initial pH is 10? Note that the total carbonate is the sum of all of the carbonate species ([H2CO3]+[HCO3] + [CO2]) present in the sample. What are the acid-base pairs responsible for buffering in this sample?
Consider exactly one litre of a hydrofluoric acid buffer solution, containing 0.800 M HF and 0.528 M F-1. Determine the pH of the buffer solution.- You may use “HA” to denote the formula of the acid.- You may make certain assumptions to simplify your calculations- Ka for hydrofluoric acid is 6.6 × 10−42. Determine by means of a full calculation the change in pH of the buffer solution that will result when 100. mL of a 1.00 × 10−2 M HCℓ solution is added to it. You must indicate all the relevant reaction equations in your working.

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