Ch20-21 Recitation part II. Read 21.9 (except 21.9c part); 21.10; 21.5; 20.8 1. From the pairs of compounds choose the one(s) which will give, upon proper mixing, single product(s) in Claisen condensation. Show them. No mechanism II and and II IV and and

Organic Chemistry
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Chapter21: Carboxylic Acid Derivatives: Nucleophilic Acyl Substitution Reactions
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Ch20-21 Recitation part II. Read 21.9 (except 21.9c part); 21.10; 21.5; 20.8
1. From the pairs of compounds choose the one(s) which will give, upon proper mixing, single
product(s) in Claisen condensation. Show them. No mechanism
and
and
II
IV
and
and
2. Show how to synthetize the following keto ester from corresponding esters and a base. Show
mechanism. Account for formation of other products.
3. Complete the synthesis
PCI3
H20
OH
A
OH
OH
NH
4. Under the following conditions, the Claisen condensation fails, explain why
NaOBu/BUOH
Transcribed Image Text:Ch20-21 Recitation part II. Read 21.9 (except 21.9c part); 21.10; 21.5; 20.8 1. From the pairs of compounds choose the one(s) which will give, upon proper mixing, single product(s) in Claisen condensation. Show them. No mechanism and and II IV and and 2. Show how to synthetize the following keto ester from corresponding esters and a base. Show mechanism. Account for formation of other products. 3. Complete the synthesis PCI3 H20 OH A OH OH NH 4. Under the following conditions, the Claisen condensation fails, explain why NaOBu/BUOH
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