1. NEtz Cbulky base) or Ko+ 2. Cla, HyO Br ОН I. NEts (bulky base) 2. Bty THF 3. NaOH, H,O2 Но 4. Br Br 1. NEtz ). OsOy, Hy Oz OH ОН 3. 5.

Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Andrei Straumanis
Chapter4: Polar Bonds, Polar Reactions
Section: Chapter Questions
Problem 12E
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How do these mechanisms with NET3 work? Would someone be able to draw out the mechanisms?

 

Specifically for the last one, I am confused because if NET3 is a base, shouldn't the double bond be the adjacent one (tetra substituted)?

1. NEtz Cbulky base) or Ko+
2. Cla, HyO
Br
ОН
I. NEts (bulky base)
2. Bty THF
3. NaOH, H,O2
Но
4.
Br
Br
1. NEtz
). OsOy, Hy Oz
OH
ОН
3.
5.
Transcribed Image Text:1. NEtz Cbulky base) or Ko+ 2. Cla, HyO Br ОН I. NEts (bulky base) 2. Bty THF 3. NaOH, H,O2 Но 4. Br Br 1. NEtz ). OsOy, Hy Oz OH ОН 3. 5.
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