Choose the best answer Ecell for Pt|H2 (p=1 atm)lH*(m)||Cl|Hg2Cl2[Hg|Pt is 0.398 V at 1.0 atm and 306.4 K. E, for the normal calomel electrode is 0.28V. Calculate the pH of solution (without
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- What Range of cathode potentials versus the saturated calomel electrode can be used to quantitatively separate Ag+ and Ni2+ by electrolytic deposition? Assume that the sample solution is initially 0.1000M in each ion and the quantitative removal of an ion is realized when only 1 part in 10000 remains undeposited. ESCE = 0.244V E0Red (Ag+) = 0.8V E0Oxid (Ni) = -0.25VA 40.00-mL aliquot of 0.05000 M HNO2 is diluted to 75.00 mL and titrated with 0.0800 M Ce4+. The pH of the solution is maintained at 1.00 throughout the titration; the formal potential of the cerium system is 1.44V a. Calculate the potential of the indicator electrode with respect to a saturated calomel reference electrode after the addition of 5.00, 10.00, 15.00, 25.00, 40.00, 49.00, 49.50, 49.60, 49.70, 49.80, 49.90, 49.95, 49.99, 50.00, 50.01, 50.05, 50.10, 50.20, 50.30, 50.40, 50.50, 51.00, 60.00, 75.00 and 90.00 mL of Cerium (IV). b. Draw a titration curve for these data. c. Generate a first- and second-derivative curve for these data. Does the volume at which the second-derivative curve crosses zero correspond to the theoretical equivalence point? Why or why not?Given the following: A cell SCE // Ag2CrO4 (saturated), CrO42- (xM) /AG is used for the determination of pCrO4- (ESCE = -0.244 V at 25 C). The half reaction at indicator electrode is: Ag2CrO4(s) + 2e- 2 Ag(s) + CrO42- (E0 = +0.446 V) What is pCrO4, given the cell potential of 0.402? What type of indicator electrode is Ag in this situation?
- Is a quantitative separation of Zn2+ and Ag+ by electrolytic deposition feasible in principle? If so what range of cathode potential versus that saturated calomel electrode can be used? Assume that the solution is initially 0.1000M in each ion and that quantitative removal of an ion is realized when only 1 part in 1000 remains undeposited E0reduction of Zn2+ = -0.76V E0oxidation of Ag = -0.8VUse the shorthand notation to describe a cell consisting of a saturated calomel reference electrode and a silver indicator electrode for the measurement of (a) pSCN. (b) pI. (c) pSO3 (d) pPO. Then, generate an equation that relates pAnion to Ecell for each of the cells. (For Ag2SO3 Ksp = 1.5 * 10-14; for Ag3PO4, K,p = 1.3 *10-20 ).Why it is necessary to platinize the electrodes of a conductivity cellbefore it is used for conductance measurement?
- Consider the titration of 25.0ml 0.0100M Sn2+ by 0.0500M Tl3+ in 1M HCl using Pt and saturated calomel electrodes , calculate E at following volumes of Tl3+ : 1, 5 and 10mlHow long would it take to titrate 1.00 mmol H2S with a current of 100.0 mA?A bare silver wire electrode is dipped into a solution 0.05M in KNO3 (supporting electrolyte) and saturated in AgBr (Ksp = 5.0 x 10-13), and connected to the back of an mV/pH meter along with a saturated calomel reference electrode. Calculate the potential of the silver indicator electrode. Calculate the cell potential.
- An ion selective electrode is utilised to determine the concentration of Ca2+ in the presence of Mg2+. The selectivity coefficient for the electrode kij is 0.015. If the concentrations of Ca2+ and Mg2+ are 50 and 500 ppm, respectively, calculate the change in potential (in mV) when the temperature of the measurement cell is increased from 20oC to 40oC.In the analysis at 25 ° C of chloride using an ion selective electrode (ISE), two 100 mL solutions were prepared. These contain 1.0129x10-2 M and 1.01239x10-3 M Cl- and yielded a potential of 20.3 mV and 79.5 mV, respectively. The value of the electrode slope in mV is:A 40.00-mL aliquot of 0.05000 M HNO2 is diluted to 75.00 mL and titrated with 0.0800 M Ce4+ . The pH of the solution is maintained at 1.00 throughout the titration; the formal potential of the cerium system is 1.44 V. Calculate the potential of the indicator electrode with respect to a saturated calomel reference electrode after the addition of 5.00 mL of cerium (IV). (Use a MW value in 4 decimal places)