Chromium is an interesting transition metal that is important in metallurgy and is also found in many oxidation states in many different types of coordination compounds. Consider the coordination compound Rb2[Cr(O)Cls] (one oxide ligand and five chloride ligands). a. Determine the oxidation state and d-configuration for the chromium atom. HINT: Use the periodic table to deduce the charge of an oxide ligand. b. State the coordination number for this coordination compound and the expected geometry. Are there any isomers expected for this compound? If there are, draw structures of the isomers. C.
Chromium is an interesting transition metal that is important in metallurgy and is also found in many oxidation states in many different types of coordination compounds. Consider the coordination compound Rb2[Cr(O)Cls] (one oxide ligand and five chloride ligands). a. Determine the oxidation state and d-configuration for the chromium atom. HINT: Use the periodic table to deduce the charge of an oxide ligand. b. State the coordination number for this coordination compound and the expected geometry. Are there any isomers expected for this compound? If there are, draw structures of the isomers. C.
Chapter21: Transition Metals And Coordination Chemistry
Section: Chapter Questions
Problem 71AE
Related questions
Question
Answer question 1; parts a,b,c,d
![Chromium is an interesting transition metal that is important in metallurgy and is
also found in many oxidation states in many different types of coordination compounds.
Consider the coordination compound Rb2[Cr(O)Cls] (one oxide ligand and five chloride
ligands).
a. Determine the oxidation state and d-configuration for the chromium atom. HINT: Use
the periodic table to deduce the charge of an oxide ligand.
b. State the coordination number for this coordination compound and the expected
geometry.
Are there any isomers expected for this compound? If there are, draw structures of the
isomers.
C.
d. Rb2[Cr(O)Cls] is observed to be reddish purple in color and have a wavelength of
maximum absorbance at 588 nm. If it were possible to make Rb2[Cr(O)(NH:)s], would
you expect the wavelength of maximum absorbance to shift to longer or shorter
wayelengths? Explain your answer.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Ffba53fc5-f280-45c2-b123-0feb9eb35059%2F520555b8-9838-4fa6-ba1f-acaea64ed14e%2F213h77_processed.jpeg&w=3840&q=75)
Transcribed Image Text:Chromium is an interesting transition metal that is important in metallurgy and is
also found in many oxidation states in many different types of coordination compounds.
Consider the coordination compound Rb2[Cr(O)Cls] (one oxide ligand and five chloride
ligands).
a. Determine the oxidation state and d-configuration for the chromium atom. HINT: Use
the periodic table to deduce the charge of an oxide ligand.
b. State the coordination number for this coordination compound and the expected
geometry.
Are there any isomers expected for this compound? If there are, draw structures of the
isomers.
C.
d. Rb2[Cr(O)Cls] is observed to be reddish purple in color and have a wavelength of
maximum absorbance at 588 nm. If it were possible to make Rb2[Cr(O)(NH:)s], would
you expect the wavelength of maximum absorbance to shift to longer or shorter
wayelengths? Explain your answer.
Expert Solution
This question has been solved!
Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.
Step by step
Solved in 3 steps with 3 images
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Recommended textbooks for you
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry: The Molecular Science
Chemistry
ISBN:
9781285199047
Author:
John W. Moore, Conrad L. Stanitski
Publisher:
Cengage Learning
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry: The Molecular Science
Chemistry
ISBN:
9781285199047
Author:
John W. Moore, Conrad L. Stanitski
Publisher:
Cengage Learning
Principles of Modern Chemistry
Chemistry
ISBN:
9781305079113
Author:
David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:
Cengage Learning
Chemistry: Principles and Practice
Chemistry
ISBN:
9780534420123
Author:
Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:
Cengage Learning
Chemistry & Chemical Reactivity
Chemistry
ISBN:
9781133949640
Author:
John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:
Cengage Learning