Deducing a rate law from the change in concentration over timeA chermistry graduate student is studying the rate of this reaction:Н,Со, (аg) - н,о (аq) +со, (aqg)She fills a reaction vessel with H,Co, and measures its concentration as thereaction proceeds:olotime[H,CO,](seconds)0.0200M10.0.00577M20.0.00337M30.0.00238 M40.0.00184MUse this data to answer the following questions.Write the rate law for this reaction.rate = k ||Ox10Calculate the value of the rate constant k.k = 0Round your answer to 2 significant digits. Also be?sure your answer has the correct unit symbol.||

Answered: Image /qna-images/answer/824d46b7-1357-4103-8218-8e10cbd3dbcc.jpg

Deducing a rate law from the change in concentration over time A chemistry graduate student is studying the rate of this reaction: H,CO, (aq) →H,0 (aq)+ CO, (aq) She fills a reaction vessel with H,Co, and measures its concentration as the reaction proceeds: time [H,Co.] (seconds) 0.0200M 團 10. 0.00577M 20. 0.00337M 30. 0.00238 M 40. 0.00184M Use this data to answer the following questions. Write the rate law for this reaction. rate = k O Calculate the value of the rate constant k. k = Round your answer to 2 significant digits. Also be sure your answer has the correct unit symbol.

Deducing a rate law from the change in concentration over time A chemistry graduate student is studying the rate of this reaction: H,CO, (aq) →H,0 (aq)+ CO, (aq) She fills a reaction vessel with H,Co, and measures its concentration as the reaction proceeds: time [H,Co.] (seconds) 0.0200M 團 10. 0.00577M 20. 0.00337M 30. 0.00238 M 40. 0.00184M Use this data to answer the following questions. Write the rate law for this reaction. rate = k O Calculate the value of the rate constant k. k = Round your answer to 2 significant digits. Also be sure your answer has the correct unit symbol.

Chemistry for Engineering Students

3rd Edition

ISBN:9781285199023

Author:Lawrence S. Brown, Tom Holme

Publisher:Lawrence S. Brown, Tom Holme

Chapter11: Chemical Kinetics

Section: Chapter Questions

Problem 11.52PAE

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Experimental data are listed here for the reaction B: Time (s) IB] (mol/L) 0.00 0.000 10.0 0.326 20.0 0.572 30.0 0.750 40.0 0.890 Prepare a graph from these data, connect the points with a smooth line, and calculate the rate of change of [B] for each 10-s interval from 0.0 to 40.0 s. Does the rate of change decrease from one time interval to the next? Suggest a reason for this result. How is the rate of change of [AJ related to the rate of change of [B] in each time interval? Calculate the rate of change of [AJ for the time interval from 10.0 to 20.0 s. What is the instantaneous rate, A[B]/Ar, when [BI = 0.750 mol/L?
The reaction 2 NO(g) + 2 H2(g) N2(g) + 2 H2O(g) was studied at 904 C, and the data in the table were collected. (a) Determine the order of the reaction for each reactant. (b) Write the rate equation for the reaction. (c) Calculate the rate constant for the reaction. (d) Find the rate of appearance of N2 at the instant when [NO] = 0.350 mol/L and [H] = 0.205 mol/L.
A study of the rate of dimerization of C4H6 gave the data shown in the table: 2C4H6C8H12 (a) Determine the average rate of dimerization between 0 s and 1600 s, and between 1600 s and 3200 s. (b) Estimate the instantaneous rate of dimerization at 3200 s from a graph of time versus [C4H6]. What are the units of this rate? (c) Determine the average rate of formation of C8H12 at 1600 s and the instantaneous rate of formation at 3200 s from the rates found in parts (a) and (b).
Phenyl acetate, an ester, reacts with water according to the equation The data in the table were collected for this reaction at 5 C. (a) Plot the phenyl acetate concentration versus time, and describe the shape of the curve observed. (b) Calculate the rate of change of the phenyl acetate concentration during the period 15.0 seconds to 30.0 seconds and also during the period 75.0 seconds to 90.0 seconds. Why is one value smaller than the other?
Experimental data are listed here for the reaction A 2 B. (a) Prepare a graph from these data; connect the points with a smooth line; and calculate the rate of change of [B] for each 10-second interval from 0.0 to 40.0 seconds. Does the rate of change decrease from one time interval to the next? Suggest a reason for this result. (b) How is the rate of change of [A] related to the rate of change of [B] in each time interval? Calculate the rate of change of [A] for the time interval from 10.0 to 20.0 seconds.
6. Phenyl acetate, an ester, reacts with water according to the equation The data in the table were collected for this reaction at 5°C. Time (s) [Phenyl acetate] (mol/L) 0 0.55 15.0 0.42 30.0 0.31 45.0 0.23 60.0 0.17 75.0 0.12 90.0 0.085 Plot the phenyl acetate concentration versus time, and describe the shape of the curve observed. Calculate the rate of change of the phenyl acetate concentration during the period 15.0 seconds to 30.0 seconds and also during the period 75.0 seconds to 90.0 seconds. Why is one value smaller than the other? What is the rate of change of the phenyl acetate concentration during the time period 60.0 seconds to 75.0 seconds? What is the instantaneous rate at 15.0 seconds?
11.51 Peroxyacetyl nitrate (PAN) has the chemical formula CtHjNOj and is an important lung irritant in photochemical smog. An experiment to determine the decomposition kinetics of PAN gave the data below. Determine the order of reaction and calculate the rate constant for the decomposition of PAN. Time, t (min) Partial Pressure of PAN (torr) 0.0 2.00 X 10~’ 10.0 1.61 X 10~} 20.0 1.30 X 10_J 30.0 1.04 X 10"’ 40.0 8.41 X 10-4 50.0 6.77 x 10-4 60.0 5.45 X 10-4
The initial rate for a reaction is equal to the slope of the tangent line at t 0 in a plot of [A] versus time. From calculus, initial rate = d[A]dt . Therefore. the differential rate law for a reaction is Rate = d[A]dt=k[A]n. Assuming you have some calculus in your background, derive the zero-, first-, and second-order integrated rate laws using the differential rate law.
Consider the decomposition reaction 2X2Y+ZThe following graph shows the change in concentration with respect to time for the reaction. What does each of the curves labeled 1, 2, and 3 represent?
Nitrogen monoxide reacts with chlorine according to the equation: 2NOCI(g)2NOCI(g) The following initial rates of reaction have been observed for certain reactant concentrations: [NO] (moI/L1) [CI2] (mol/L) Rate (moI/L/h) 0.50 0.50 1.14 1.00 0.50 4.56 1.00 1.00 9.12 What is the rate equation that describes the rate’s dependence on the concentrations of NO and CI2? What is the rate constant? What are the orders with respect to each reactant?