Determine the rate law equation for the following mechanism using pre-equilibrium approximation. k₂ Cl₂ 2cl- (1) fast, equilibrium k₂ ką (2) CI+CHCI → HCI + CCI3 slow k4 (3) CCl3 + Cl → CCI₂ fast

Determine the rate law equation for the following mechanism using pre-equilibrium approximation. k₂ Cl₂ 2cl- (1) fast, equilibrium k₂ ką (2) CI+CHCI → HCI + CCI3 slow k4 (3) CCl3 + Cl → CCI₂ fast

Chemistry: Principles and Practice

3rd Edition

ISBN:9780534420123

Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer

Publisher:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer

Chapter13: Chemical Kinetics

Section: Chapter Questions

Problem 13.75QE

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Question

Determine the rate law equation for the following mechanism using pre-equilibrium approximation.
k₂
Cl₂ 2cl-
(1)
fast, equilibrium
k₂
ką
(2)
CI+CHCI → HCI + CCI3
slow
k4
(3)
CCl3 + Cl → CCI₂
fast

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