Devise the electrochemical cell in which the cell reaction is Cu2+(aq.) + 2Cl-(aq.) + 2 Ag(s) 2 AgCl(s) + Cu(s) Write down the half-cell reactions for the corresponding electrodes, and the Nernst equation. Calculate the standard Gibbs free energy for the cell reaction, the equilibrium constant, and the standard potential of the cell from the thermodynamic data below Substance Cu2+(aq.) Cl-(aq.) AgCl(s) DfG0(kJ/mol) 65.5 -131 -110 c) Given that the standard potential of the Silver/Silver chloride electrode is 0.22V, calculate the standard potential of the Cu(s)/ Cu2+(aq.) electrode.
Devise the electrochemical cell in which the cell reaction is Cu2+(aq.) + 2Cl-(aq.) + 2 Ag(s) 2 AgCl(s) + Cu(s) Write down the half-cell reactions for the corresponding electrodes, and the Nernst equation. Calculate the standard Gibbs free energy for the cell reaction, the equilibrium constant, and the standard potential of the cell from the thermodynamic data below Substance Cu2+(aq.) Cl-(aq.) AgCl(s) DfG0(kJ/mol) 65.5 -131 -110 c) Given that the standard potential of the Silver/Silver chloride electrode is 0.22V, calculate the standard potential of the Cu(s)/ Cu2+(aq.) electrode.
Principles of Modern Chemistry
8th Edition
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Chapter17: Electrochemistry
Section: Chapter Questions
Problem 14P
Related questions
Question
- Devise the
electrochemical cell in which the cell reaction is
Cu2+(aq.) + 2Cl-(aq.) + 2 Ag(s) 2 AgCl(s) + Cu(s)
- Write down the half-cell reactions for the corresponding electrodes, and the Nernst equation.
- Calculate the standard Gibbs free energy for the cell reaction, the equilibrium constant, and the standard potential of the cell from the
thermodynamic data below
Substance Cu2+(aq.) Cl-(aq.) AgCl(s)
DfG0(kJ/mol) 65.5 -131 -110
- c) Given that the standard potential of the Silver/Silver chloride electrode is 0.22V, calculate the standard potential of the Cu(s)/ Cu2+(aq.) electrode.
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