Draw the products formed when each carbonyl compound reacts with the following amines: (1] CH,CH,CH,NH2; [2] (CH3CH2)NH. cOCI 요요 b. .C. CH a. CH3
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![Draw the products formed when each carbonyl compound reacts with the following amines:
(1] CH,CH,CH,NH2; [2] (CH3CH2)NH.
cOCI
요요
b.
.C.
CH
a.
CH3](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F77107ffb-7676-401f-bda3-a8d9f2c8b441%2F47a8db06-1758-4d2d-a3f8-6dce2d033937%2F3zkd53j_processed.png&w=3840&q=75)
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- What carboxylic acid and amine are needed to synthesize the pain reliever phenacetin? Phenacetin was once a component of the over-the-counter pain reliever APC (aspirin, phenacetin, caffeine), but it is no longer used because of its kidney toxicity.Rank the following amines in order of basicity.Draw the products formed when each amine is treated with [1] CH3I (excess); [2] Ag2O; [3] Δ. Indicate the major product when a mixture results.
- Draw the major product formed by treating each amine with excess CH3I, followed by Ag2O, and then heat.. Explain how you would rank the amines given below according to their basicity, together with the reasons.CH3NH2 (CH3)2NH (CH3)3NExplain why the boiling point of propanamide, CH3CH2CONH2, is considerably higher than the boiling point of N,Ndimethylformamide, HCON(CH3)2 (213 °C vs. 153 °C), even though both compounds are isomeric amides.
- What amide(s) can be used to prepare each amine by reduction?Synthadotin is a promising anticancer drug in clinical trials. a.Identify the functional groups. b.Classify any amine or amide as 1°, 2°, or 3°. c.At which sites can synthadotin hydrogen bond to another molecule like itself? d. Label two nucleophilic sites. e. Label two electrophilic sites. f. What product is formed when synthadotin is treated with HCl?Safrole, which is isolated from sassafras (Problem 21.33), can be converted to the illegal stimulant MDMA (3,4- methylenedioxymethamphetamine, “Ecstasy”) by a variety of methods. (a) Devise a synthesis that begins with safrole and uses a nucleophilic substitution reaction to introduce the amine. (b) Devise a synthesis that begins with safrole and uses reductive amination to introduce the amine.
- Stanozolol is an anabolic steroid that promotes muscle growth. Althoughstanozolol has been used by athletes and body builders, many physicaland psychological problems result from prolonged use and it is bannedin competitive sports. Explain why the pKa of the N—H bond in the pyrazole ring iscomparable to the pKa of the O—H bond, making it considerably moreacidic than amines such as CH3NH2 (pKa = 40).Rank the labeled N atoms in the anticancer drug imatinib (trade nameGleevec) in order of increasing basicity. Imatinib, sold as a salt withmethanesulfonic acid (CH3SO3H), is used for the treatment of chronicmyeloid leukemia as well as certain gastrointestinal tumors.based on this video: on Hinsberg Test Tests for Amines - MeitY OLabs (8.5min) https://www.youtube.com/watch?v=j5jgMUWri8U Write the reaction (two-step, in skeletal) of each test amine when tested in the Hinsberg Test.
