Q: Which of the following compounds is the most basic? A. p-methoxyaniline B. aniline C.…
A: As we know that aromatic amines are less basic than the alipahatic amine , because of resonance…
Q: Explain the reactivity and orientation effects observed in each heterocycle.a. Pyridine is less…
A: Aromatic compounds generally shows electrophilic substitution reactions. In electrophilic…
Q: Draw a stepwise mechanism for the following Friedel-Crafts acylation. CH3 AICI, + HCI CH
A: Given reaction,
Q: Explain why protonating aniline has a dramatic effect on the compound’s UV spectrum, whereas…
A: Protonation is the addition of a proton molecule to make a conjugate acid. Each and every structure…
Q: ank the following acid derivative classes in order of increasing reactivity with the same…
A: 8) the increasing order of reactivity with the same nucleophile is:
Q: What type of product would form when LDA( strong base/weak nucleophile) is reacted with( methyl…
A: There is no reaction between methyl halide and LDA.
Q: Describe how an electron donating group on an aromatic ring affects the proton chemical shifts of…
A: Since your question has multiple parts, we will answer the first question for you. If you want…
Q: proton on an NMR spectrum. An alcohol proton is deshielded as compared to a(n) carboxylic acid…
A:
Q: HNO3 `NH `NH H2SO4 NO2 Acetanilide para-Nitroacetanilide
A: We have to draw two alternative isomers of nitroacetanilide and suggest two reasons why, during this…
Q: Rank the following from LEAST TO MOST reactive towards electrophilic aromatic substitution: 1.…
A: A question based on aromatic compounds that is to be accomplished.
Q: Methyl benzoate + Nitric acid + Sulfuric acid => A.) p-methyl-thiophenol B.)…
A: The given reaction is, Methyl benzoate + Nitric acid + Sulfuric acid =>
Q: Starting with Benzene (or naphthalene or biphenyl) Show a sequence of 3 electrophilic aromatic…
A: Benzene is an aromatic compound. The molecular formula of benzene is C6H6. It contains three double…
Q: Which amide would you treat with LIAIH4 to prepare the following compound? -CH2NHCH3 -CH2-Ċ-NH2…
A: Amides are reduced to amine on reaction with lithium aluminium hydride to give the corresponding…
Q: n-acetylazoles go through hydrolysis more than regular amides. propose a reason for the reactivity…
A: Amide hydrolysis is not so easy because of the donating ability of lone pair of electrons on…
Q: ameand Draw the structures of all possible chemical (Electrophilic aromatic substitution) reactions…
A: We know that Electrophilic aromatic substitution : Electrophilic aromatic substitution is an…
Q: Esters and amides are most easily made by nucleophilic acyl substitution reactions on… A. alcohols…
A:
Q: f. propanoic anhydride g. cyclohexyl propanoate h. 3-methylhexanoyl chloride i.…
A:
Q: Draw the rearrangement-elimination product of 2-ethyl-3-methyl-2-(1-methylethyl)butan-1-ol, sulfuric…
A: In presence of strong acid and heat, water molecule leaves out the system and carbocation is formed.…
Q: The synthesis of acetanilide from aniline and acetic anhydride follows which mechanism?…
A: Organic compound undergo different mechanistic pathway to form product
Q: Which of the following is expected to be the MOST reactive towards electrophilic aromatic…
A: Two questions base on introduction to organic chemistry that is to be accomplished.
Q: Predict the Zaitsev product 1. pentan-2-ol = _____ + H2O 2. hexan-2-ol = _____ + H2O Predict Anti…
A:
Q: NH2 HO Atenolol Tenormin® Below is a two-step reaction sequence. What are the steps in the…
A:
Q: `NH HNO3 `NH H2SO4 NO2 Acetanilide para-Nitroacetanilide
A: We have to draw two alternative isomers of nitroacetanilide and suggest two reasons why, during this…
Q: Example #1: Predict the substitution pattern when this compound undergoes a sulfonation reaction. |…
A: • Sulfonation reaction Electrophile is SO3⊕H.• Friedel-Crafts alkylation Electrophile is → R-⊕
Q: Explain why imidazolides are much more reactive than other amides in nucleophilic acyl substitution.
A: It is known that, imidazolides are much more reactive than other amides in nucleophilic acyl…
Q: Name and draw the structures of all the possible chemical (electrophilic aromatic substitution)…
A: The substitution reaction on the benzene ring of acetophenone occurs via electrophilic aromatic…
Q: Explain why benzaldehyde is less reactive than cyclohexanecarbaldehyde towards nucleophilic attack.
A: Benzaldehyde is aromatic is nature whereas Cyclohexanecarbaldehyde is not aromatic.
Q: Explain the reactivity and orientation effects observed in each heterocycle. a. Pyridine is less…
A: Aromatic compounds like benzene show some specific chemical reactions like electrophilic…
Q: Match each item to a choice: Choices: alkene Reductive amination Curtius rearrangement Hoffman…
A: Match the following of amine reactions
Q: Which of the following can form a carbinolamine intermediate with ammonia? a Bromoethane b…
A:
Q: DMSO KOt-Bu KBr + major product & NaCl a = Electrophilic addition d = SN2 Nucleophilic substitution…
A: The mechanism carried out in the given reactions are:
Q: Which solvent would make the bromination through electrophilic aromatic substitution faster?…
A: Generally bromination through electrophilic aromatic substitution is more efficient in polar…
Q: 2-Methyl-2-butanol reacts with hydrogen bromide via a(n) E2 mechanism SN1 mechanism E1…
A:
Q: Give the major product from A-E Give the major product trom A-E. the HBr D H2O2 H2 A Ni Ch H/H2O E C…
A: Different reagents are used for the synthesis of a compound (product) from the different compounds…
Q: Arrange the compounds in each set in the order of decreasing reactivity (fastest to | slowest)…
A: We have to arrange the following given compounds in each set in the order of decreasing reactivity…
Q: 5.18 NH2 N=N (i) HCI, NaNO2 (ii) PHNME2 `CO2H CO2H `NM@2 Amines are good nucleophiles (nitrogen…
A:
Q: How do you account for the fact that N-phenylacetamide (acetanilide) is less reactive toward…
A: Given statement, N-phenylacetamide is less reactive toward electrophilic aromatic substitution…
Q: Identify the mechanism by which each of the reactions above proceeds from among the mechanisms…
A: According to the reaction mechanism option (f) carbonyl nucleophilic addition is correct answer.
Q: Name and Draw the structures of all possible chemical (Electrophilic aromatic substitution)…
A: Since we only answer up to 3 sub-parts, we’ll answer the first 3. Please resubmit the question and…
Q: OH - NH, Br2/KOH →product; 1. (a-hydroxy amide) Product of this Hoffmann bromamide reaction is : OH…
A:
Q: 8. The structures of pyrrole and pyrrolidine are shown in the box. NH NH рyrrole руrrolldine What is…
A: ->the species which can donate it's loan pair to acid can acts as base.where the availability of…
Q: Please draw out the 2 reaction schemes: Ethyl diacetoacetate + hydrazine = pyrazole Ethyl…
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Q: Which one is INCORRECT? a.Br2 : electrophilic aromatic substitution b.Neutral KMnO4 : oxidation…
A: 1.The reaction of benzene with Br2 is an example of electrophilic aromatic substitution. Bromine…
Q: Rank the compounds in each group according to their reactivity toward electrophilic substituti 1 =…
A: Rate of Electrophilic substitution reaction increases if benzene ring is attached to the electron…
Q: Draw a stepwise mechanism for the following reaction: HBr HO, Br Part 1: HOBR Br H20 HO view…
A: Given reaction is preparation of alkyl bromide from alcohol It is an example of nucleophilic…
Q: Draw the products of the following reactions w given starting material 1. HCl 2. KMnO4 3. BH3…
A: We have to find out the product when 1-ethynylcyclohexane react with different reagent. 1) with HCl…
Q: b. Rank by rate of electrophilic aromatic substitution. The compound that reacts the fastest in an…
A: The answer is given below:
Q: Which compound will react most rapidly with acetaldehyde? A.propylmagnesium chloride B.cyclopropyl…
A: Acetaldehyde show nucleophilic addition in which nucleophile attack on carbonyl carbon.
Q: Br NaOH heat Draw E1 Major Product + Draw Minor E1 Product
A:
Explain the reactivity order of the given de/activating groups:
- alkyl
- amide
- bromine
- hydroxyl
- methoxy
- phenoxy
Step by step
Solved in 2 steps
- Draw a detailed mechanism for the FeBr3@catalyzed reaction of ethylbenzene with bromine, and show why the sigma complex (and the transition state leading to it) is lower in energy for substitution at the ortho and para positions than it is for substitution at the meta position.Which reaction below give a par of diastereomers and Why?Identify A–E.
- Propose a mechanism for the following reaction that explains why the configuration of the asymmetric center in the reactant is retained in the product:The -Cl group is considered a .... Ortho/Para Directing Activator Ortho/Para Directing Deactivator Meta Directing DeactivatorThe signal for the acid proton of the product shows at d=-11.5 ppm in CDCl3 while it is found at d=-12.5 ppm in DMSO-d6. what would be the best explanation for that? Williamson Ether Synthesis
- The -NHCOCH3 group is considered a .... Ortho/Para Directing Activator Ortho/Para Directing Deactivator Meta Directing DeactivatorExplain the E2 mechanism (bimolecular elimination) of of Elimination ?Draw the coupling product formed when each attached pair of compounds is treated with Pd(OAc)2, P(o-tolyl)3, and Et3N.
- The cyano (-CN) group is considered a .... Ortho/Para Directing Activator Ortho/Para Directing Deactivator Meta Directing DeactivatorList the following in increasing order of nucleophilic strength. CH3COO-, H2O, CH3O-, OH-, CH3CH20-Explain why two different products are formed from disrotatory ring closure of (2E,4Z,6Z)-octatriene, but only one product is formed from disrotatoryring closure of (2E,4Z,6E)-octatriene.
