Square planar Ir complexes have been widely studied in organometallic catalysis. Provided the following isomers answer the following questions: CN CN ........ Ir CN NC CI Isomer A Isomer B What is the point group of each isomer? C2v D2h Isomer A: Isomer B: а. Determine the reducible and irreducible representations corresponding to the CN stretching of Isomer A. b. Determine the reducible and irreducible representations corresponding to the CN stretching of Isomer B. с. With the information learned, can these 2 isomers be distinguished with IR spectroscopy?

Square planar Ir complexes have been widely studied in organometallic catalysis. Provided the following isomers answer the following questions: CN CN ........ Ir CN NC CI Isomer A Isomer B What is the point group of each isomer? C2v D2h Isomer A: Isomer B: а. Determine the reducible and irreducible representations corresponding to the CN stretching of Isomer A. b. Determine the reducible and irreducible representations corresponding to the CN stretching of Isomer B. с. With the information learned, can these 2 isomers be distinguished with IR spectroscopy?

Physical Chemistry

2nd Edition

ISBN:9781133958437

Author:Ball, David W. (david Warren), BAER, Tomas

Publisher:Ball, David W. (david Warren), BAER, Tomas

Chapter13: Introduction To Symmetry In Quantum Mechanics

Section: Chapter Questions

Problem 13.68E

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