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Write the structures for the major products from the following reactions.
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- Over time, as their free fatty acid (FFA) content increases,edible fats and oils become rancid. To measure rancidity, the fator oil is dissolved in ethanol, and any FFA present is titrated withKOH dissolved in ethanol. In a series of tests on olive oil, a stocksolution of 0.050 Methanolic KOH was prepared at 25C, storedat 0C, and then placed in a 100-mL buret to titrate any oleic acid[CH₃(CH₂)₇CH=CH(CH₂)₇COOH] present in the oil. Each offour 10.00-g samples of oil took several minutes to titrate: thefirst required 19.60 mL, the second 19.80 mL, and the third and fourth 20.00 mL of the ethanolic KOH.(a) What is the apparent acidity of each sample, in terms of mass% of oleic acid? (Note:As the ethanolic KOH warms in the bu-ret, its volume increases by a factor of 0.00104/C.)(b) Is the variation in acidity a random or systematic error? Ex-plain.(c) What is the actual acidity? How would you demonstrate this?What is the value (g) of the reduced mass of HF? A.)20 B.)0.95 C.)1.05 D.)3.80 × 10^2Sodium carbonate is a reagent that may be used to standardizeacids in the same way. In such standardization it was found that a 0.432-g sample ofsodium carbonate required 22.3 mL of a sulfuric acid solution to reach the end point forthe reaction.Na2CO3(aq) + H2SO4(aq) -----> H2O(l) + CO2(g) + Na2SO4(aq)What is the molarity of the H2SO4?
- Drug A dissociates into four ions to the extent of 70%. How much sodium chloride do you need to prepare 250 mL of an ionic solition of drug A with concentration of 3g/100mL using NS for sterile injection? MW of Drug A= 892.54 (assume final volume will be qs with sterile water for injection) a. 155.9 ml NaCl b. 62.37 mL NaCl c. 146.6 mL NaCl d. 218.33 mL NaClLakes that have been acidified by acid rain can be neutralizedby the addition of limestone (CaCO3). How muchlimestone in kilograms would be required to completelyneutralize a 5.2 * 109-L lake containing 5.0 * 10-3 g ofH2SO4 per liter?In the standardization of HCl using pure anhydrous sodium carbonate as the primarystandard for methyl orange as an indicator, 1.0 mL HCl was found to be equivalent to 0.05gof sodium carbonate (MW =106). The normality of HCl is:
- A 12.7g sample of vinegar is titrated. It requires 19.75 mL of 0.205 M NaOH to neutralize the acetic acid (CH3COOH) in the vinegar. Calculate the weight percent (w/w) of acetic acid in the vinegar. Note: 1 mole of base neutralizes 1 mole of acid.0.250 g of aluminum sulfate is dissolved in enough water to make 150 mL of solution.a. How many equivalents of sulfate ion (SO42-) are in one mole of aluminum sulfate when itdissolves?b. What is the concentration of sulfate in (Eq/L)?c. How many equivalents (Eq) of SO42-are contained in 0.0280 L of the above aluminumsulfate solution?d. How many liters (L) of this aluminum sulfate solution would contain 0.0025 equivalents Eq of SO4 2-2,4-Dichlorophenoxyacetic acid ("2,4-D") is a widely used herbicide with the molecular formula C8H6Cl2O3C8H6Cl2O3. The pKapKa of 2,4-D is 2.73. A certain water-based herbicide product contains 130 gL−1gL−1 of 2,4-D. What is the pHpH of the 2,4-D solution?
- Calculate the weight of pure sodium carbonate that is necessary to prepare 2.806 L of 0.223 N Na2CO3 (105.99 g/mol) from the primary-standard solid. Assume the solution is to be used for titrations in which the reaction is: CO32- + 2H+ ----> H2O + CO2 Express you answers in 3 decimal placesA sample of pure sodium oxalate weighing 0.1050 g is ignited [Na2C2O4 (s) --> Na2CO3 (s) + CO (g)] and the resulting product requires 15.00 mL of a solution of H2SO4 for complete neutralization. What is the normality of the acid? MM of Na2CO3 = 106.0 g/molMM of Na2C2O4 = 134.0 g/molMM of CO = 28.01 g/molMM of H2SO4 = 98.08 g/molWhen 3.00 g of sodium hydroxide (NaOH) was dissolved in 100.00 g of water a value of 11.00oC was obtained for ΔT. 1. Calculate the molarity of the sodium hydroxide solution? _____ 2. Calculate the value (calories) for the heat of solution of 3.00 g of NaOH? ______ 3. Calculate the number of calories that would be produced if one mole of sodium hydroxide was dissolved. (ΔHsolnNaOH)? ______