How will mistakenly using solution 1 to calibrate the spectrophotometer, instead of the blank affect the calcualted concentration of FESCN2+ at equilibrium and the calculated concentrations of Fe3+ and SCN- uncomplexed at equilibrium?  The blank contained 5.00mL of 0.00200 M Fe(NO3)3 (in 0.1M HNO3) and 5.00mL of 0.1 M HNO3. Solution 1 contained 5.00mL of Fe(NO3)3 (in 0.1M HNO3), 1.00mL of 0.00200 M NaSCN (in 0.1 M HNO3) and 4.00mL 0.1M HNO3.  Fe3+(aq)+SCN-(aq)->FeSCN2+(aq)

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Mass Spectrometry

This process is an instrumental method in which a sample is changed to fast moving positive ions by electron bombardment. The charged particles vary due to their different mass to charge ratio and are estimated with the help of this difference. It is also called mass spectroscopy.