10 mL of an aqueous solution containing 1 mM Fe(NO3)2 was mixed with 20 ml. of another another aqueous solution containing 0.3 M 1,10-phenanthroline (phen). Phen undergoes a series of complexation reactions with Fe in solution: Fe+ + phen Fe(phen)+ Fe(phen)2+ + phen Fe(phen), Fe(phen)," log B-5.86 2+ log B = 11.11 Fe(phen)2+ + phen 2+ log Ba = 21.14

Fundamentals Of Analytical Chemistry
9th Edition
ISBN:9781285640686
Author:Skoog
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Chapter16: Applications Of Neutralization Titrations
Section: Chapter Questions
Problem 16.20QAP
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4.
10 mL of an aqueous solution containing 1 mM Fe(NO)2 was mixed with 20 mL of another
another aqueous solution containing 0.3 M 1,10-phenanthroline (phen). Phen undergoes a series of
complexation reactions with Fe in solution:
Fe+ + phen
Fe(phen)2+
Fe(phen),"
log B1 = 5.86
Fe(phen)2+ + phen
Fe(phen)22+ + phen
2+
log Ba = 11.11
- Fe(phen),+
log Ba = 21.14
Calculate the final concentration of all species in this solution, making any reasonable approzimations
you can.
Transcribed Image Text:4. 10 mL of an aqueous solution containing 1 mM Fe(NO)2 was mixed with 20 mL of another another aqueous solution containing 0.3 M 1,10-phenanthroline (phen). Phen undergoes a series of complexation reactions with Fe in solution: Fe+ + phen Fe(phen)2+ Fe(phen)," log B1 = 5.86 Fe(phen)2+ + phen Fe(phen)22+ + phen 2+ log Ba = 11.11 - Fe(phen),+ log Ba = 21.14 Calculate the final concentration of all species in this solution, making any reasonable approzimations you can.
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