If 1.000 ml. of a solution of KMn04 is equiva- lent to 0.1000 millimole of NaCHO2 (sodium formate) in the fol- lowing titration: 3CHO2- + 2MnO-  + H2O  -> 3CO2 + 2MnO2 + 5OH-, what is the value of the KMnO4 in terms of grams of CaO in the volumetric method for calcium in which that element is precipitated as CaC2 4 .H2O and the precipitate is filtered, dis- solved in dilute H2S04 , and the oxalate titrated with permanganate?

Fundamentals Of Analytical Chemistry
9th Edition
ISBN:9781285640686
Author:Skoog
Publisher:Skoog
Chapter16: Applications Of Neutralization Titrations
Section: Chapter Questions
Problem 16.20QAP
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If 1.000 ml. of a solution of KMn04 is equiva- lent to 0.1000 millimole of NaCHO2 (sodium formate) in the fol- lowing titration: 3CHO2- + 2MnO-  + H2O  -> 3CO2 + 2MnO2 + 5OH-, what is the value of the KMnO4 in terms of grams of CaO in the volumetric method for calcium in which that element is precipitated as CaC2 4 .H2O and the precipitate is filtered, dis- solved in dilute H2S04 , and the oxalate titrated with permanganate?

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