In the method of initial rates, only a small amount of reagent is used up (the change in concentration is small compared to the total concentration).  The elapsed time is used to calculate the rate.  Why is this more accurate than calculating the rate from the amount of time required to use up all of the reagent?  (Hint:  What happens to the rate as the concentration decreases?)

Chemistry for Today: General, Organic, and Biochemistry
9th Edition
ISBN:9781305960060
Author:Spencer L. Seager, Michael R. Slabaugh, Maren S. Hansen
Publisher:Spencer L. Seager, Michael R. Slabaugh, Maren S. Hansen
Chapter8: Reaction Rates And Equilibrium
Section: Chapter Questions
Problem 8.20E: In each of the following, which reaction mechanism assumption is apparently being violated? Explain...
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 In the method of initial rates, only a small amount of reagent is used up (the change in concentration is small compared to the total concentration).  The elapsed time is used to calculate the rate.  Why is this more accurate than calculating the rate from the amount of time required to use up all of the reagent?  (Hint:  What happens to the rate as the concentration decreases?)

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