Include units for all quantities you calculate. Keep intermediate results in your calculator to avoid round-off error and report their values with 2 or 3 extra non-significant digits. Report the final molar enthalpy change with an appropriate number of significant digits. 1. Use the total volume of solution and its density to calculate the mass of the final solution: Density = 1.02 g ml. at 20 °C Volume of final solution/mL = Mass of final solution = 2. Use the mass of the final solution, AT, and the specific heat capacity of the solution to calculate the heat absorbed by the solution. Mass of final solution /g = Heat absorbed by solution=

Chemistry: Principles and Reactions
8th Edition
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:William L. Masterton, Cecile N. Hurley
Chapter8: Thermochemistry
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Part A - AHfor Hydrochloric Acid reacting with Aqueous Sodium Hydroxide.
PART A - AHfor Hydrochloric Acid reacting with aqueous Sodium Hydroxide.
For students with student numbers ending in 1, 2, 4, 5, 7, 8, or 0.
Type of calorimeter used: M white
O transparent
O blue
(see page 96)
NaOH(aq) + HСКаq) —> NaCЦаq) + Hz0()
Concentration of HCl(aq):
1.00 mol/L
Concentration of NaOH(aq): 1.00 mol/L
or
он (аq) + H'(aq) > Н200)
Elapsed time / min
0.5
1.0
1.5
2.0
2.5
1.
Clean and dry the calorimeter.
Temperature of aqueous NaOH / °C
23.6
23.6
23.7
23.7
23.7
23.7
2.
Dispense 60 mL of the standardised sodium hydroxide solution directly into the dry, clean calorimeter.
3.
Dispense 50 mL of the standardised hydrochloric acid directly into a clean, dry beaker. Record in pen the exact
concentration of the acid used onto your results page.
Elapsed time / min
3.0
3.5
4.0
4.5
5.0
5.5
4.
Temperature of HCI / °C
23.8
23.8
23.8
23.8
23.7
23.7
Starting timing (preferably using a stopwatch on a phone or tablet, or a real watch) and measure and record to 0.1 °C
the temperature of the sodium hydroxide solution at 0.5 minute intervals for a total of 6 measurements. Wash and dry
Elapsed time at mixing = 6.0 min (it is important to mix the solutions al exactly 6.0 minules and then stir thoroughly.)
the thermometer. Next, measure and record the temperature of the hydrochloric acid solution at 0.5 minute intervals for
a total of 6 measurements.
Elapsed time / min
6.5
7.0
7.5
8.0
8.5
9.0
9.5
10.0
10.5
11.0
At time = 6.0 minutes (exactly, not earlier, not later), add the hydrochloric acid solution to the sodium hydroxide solution
in the calorimeter. Mix well using a stirring rod or spatula and stir the solution for 15 seconds.
5.
Temp. of mixture / °C
28.6
29.5
29.4
29.3
29.2
29.1
29.0
29.0
28.9
28.8
Caution: Do not use the thermometer to stir the solution.
Calculation of Enthalpy of Neutralisation
6.
At time = 6.5 minutes, (and at further 0.5 minute intervals), measure the temperature of the solution. Stir the solution
Include units for all quantities you calculate. Keep intermediate results in your calculator to avoid round-off error and report
their values with 2 or 3 extra non-significant digits. Report the final molar enthalpy change with an appropriate number of
significant digits.
between the temperature measurements. Continue to measure the temperature until a steady decrease in temperature is
noted or until time = 11.0 minutes.
Note: In order to obtain a smooth temperature curve you must stir the solution continuously between temperature
measurements and keep the thermometer in the solution the whole time.
1.
Use the total volume of solution and its density to calculate the mass of the final solution:
Rinse (under the tap) the temperature probe on the thermometer and dry it.
Volume of final solution/mL =
Density = 1.02 g mL at 20 °C
7.
8.
Obtain a piece of blue litmus paper and a piece of red litmus paper. Transfer a drop of the final solution onto both pieces
Mass of final solution =
of litmus paper. Use the colours to determine whether the resultant solution is acidic or basic and record this in your
2.
Use the mass of the final solution, AT, and the specific heat capacity of the solution to calculate the heat absorbed by the
report.
solution.
9. Graph the results on the results page. Be sure to allow sufficient range on the temperature axis so that the temperature
at the time of mixing fits on the graph.
- 4.04 J g K
Mass of final solution /g =
10. Extrapolate your lines to the time of mixing (time = 6.0 minutes) and determine the change in temperature as shown on
the graph in the introduction.
Heat absorbed by solution =
11. Calculate the enthalpy change for the reaction by completing the calculations in the results pages.
Transcribed Image Text:Part A - AHfor Hydrochloric Acid reacting with Aqueous Sodium Hydroxide. PART A - AHfor Hydrochloric Acid reacting with aqueous Sodium Hydroxide. For students with student numbers ending in 1, 2, 4, 5, 7, 8, or 0. Type of calorimeter used: M white O transparent O blue (see page 96) NaOH(aq) + HСКаq) —> NaCЦаq) + Hz0() Concentration of HCl(aq): 1.00 mol/L Concentration of NaOH(aq): 1.00 mol/L or он (аq) + H'(aq) > Н200) Elapsed time / min 0.5 1.0 1.5 2.0 2.5 1. Clean and dry the calorimeter. Temperature of aqueous NaOH / °C 23.6 23.6 23.7 23.7 23.7 23.7 2. Dispense 60 mL of the standardised sodium hydroxide solution directly into the dry, clean calorimeter. 3. Dispense 50 mL of the standardised hydrochloric acid directly into a clean, dry beaker. Record in pen the exact concentration of the acid used onto your results page. Elapsed time / min 3.0 3.5 4.0 4.5 5.0 5.5 4. Temperature of HCI / °C 23.8 23.8 23.8 23.8 23.7 23.7 Starting timing (preferably using a stopwatch on a phone or tablet, or a real watch) and measure and record to 0.1 °C the temperature of the sodium hydroxide solution at 0.5 minute intervals for a total of 6 measurements. Wash and dry Elapsed time at mixing = 6.0 min (it is important to mix the solutions al exactly 6.0 minules and then stir thoroughly.) the thermometer. Next, measure and record the temperature of the hydrochloric acid solution at 0.5 minute intervals for a total of 6 measurements. Elapsed time / min 6.5 7.0 7.5 8.0 8.5 9.0 9.5 10.0 10.5 11.0 At time = 6.0 minutes (exactly, not earlier, not later), add the hydrochloric acid solution to the sodium hydroxide solution in the calorimeter. Mix well using a stirring rod or spatula and stir the solution for 15 seconds. 5. Temp. of mixture / °C 28.6 29.5 29.4 29.3 29.2 29.1 29.0 29.0 28.9 28.8 Caution: Do not use the thermometer to stir the solution. Calculation of Enthalpy of Neutralisation 6. At time = 6.5 minutes, (and at further 0.5 minute intervals), measure the temperature of the solution. Stir the solution Include units for all quantities you calculate. Keep intermediate results in your calculator to avoid round-off error and report their values with 2 or 3 extra non-significant digits. Report the final molar enthalpy change with an appropriate number of significant digits. between the temperature measurements. Continue to measure the temperature until a steady decrease in temperature is noted or until time = 11.0 minutes. Note: In order to obtain a smooth temperature curve you must stir the solution continuously between temperature measurements and keep the thermometer in the solution the whole time. 1. Use the total volume of solution and its density to calculate the mass of the final solution: Rinse (under the tap) the temperature probe on the thermometer and dry it. Volume of final solution/mL = Density = 1.02 g mL at 20 °C 7. 8. Obtain a piece of blue litmus paper and a piece of red litmus paper. Transfer a drop of the final solution onto both pieces Mass of final solution = of litmus paper. Use the colours to determine whether the resultant solution is acidic or basic and record this in your 2. Use the mass of the final solution, AT, and the specific heat capacity of the solution to calculate the heat absorbed by the report. solution. 9. Graph the results on the results page. Be sure to allow sufficient range on the temperature axis so that the temperature at the time of mixing fits on the graph. - 4.04 J g K Mass of final solution /g = 10. Extrapolate your lines to the time of mixing (time = 6.0 minutes) and determine the change in temperature as shown on the graph in the introduction. Heat absorbed by solution = 11. Calculate the enthalpy change for the reaction by completing the calculations in the results pages.
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