NH31/2 N2 + 3/2 H2 the following data were obtained: [NH3), M seconds 2.30x10-3 1.15x103 5.75x104 2.88×104 442 662 773 Hint: It is not necessary to graph these data. (1) The observed half life for this reaction when the starting concentration is 2.30x103 M is s and when the starting concentration is 1.15x10-3 M is (2) The average rate of disappearance of NH3 from t=0 s to t= 442 s is ]Ms'. (3) The average rate of disappearance of NH3 from t= 442 s to t= 662 s is |Ms! (4) Based on these data, the rate constant for this v order reaction is Ms!

Principles of Modern Chemistry
8th Edition
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Chapter18: Chemical Kinetics
Section: Chapter Questions
Problem 7P
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Question
In a study of the decomposition of ammonia on a tungsten surface at 1100 °C
NH31/2 N2 + 3/2 H,
the following data were obtained:
[NH3], M
5.75x10-4
662
2.88×10-4
773
2.30x10-3
1.15x103
seconds
442
Hint: It is not necessary to graph these data.
(1)
The observed half life for this reaction when the starting concentration is 2.30×103 M is
s and when the starting concentration is 1.15x10-3 M is
(2)
The average rate of disappearance of NH3 from t=0 s to t= 442 s is
|Ms.
(3)
The average rate of disappearance of NH3 from t= 442 s to t= 662 s is
]Ms!
(4)
Based on these data, the rate constant for this
order reaction is
Ms
Transcribed Image Text:In a study of the decomposition of ammonia on a tungsten surface at 1100 °C NH31/2 N2 + 3/2 H, the following data were obtained: [NH3], M 5.75x10-4 662 2.88×10-4 773 2.30x10-3 1.15x103 seconds 442 Hint: It is not necessary to graph these data. (1) The observed half life for this reaction when the starting concentration is 2.30×103 M is s and when the starting concentration is 1.15x10-3 M is (2) The average rate of disappearance of NH3 from t=0 s to t= 442 s is |Ms. (3) The average rate of disappearance of NH3 from t= 442 s to t= 662 s is ]Ms! (4) Based on these data, the rate constant for this order reaction is Ms
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