an a study of the gas phase decomposition of phosphine at 120 °C PH3(g)1/4 P4(g) + 3/2 H2(g) the concentration of PH3 was followed as a function of time. It was found that a graph of In[PH3] versus time in seconds gave a straight line with a slope of -2.81×10-2 s1 and a y-intercept of -4.31. Based on this plot, the reaction is | order in PH3 and the rate constant for the reaction is s1.

Fundamentals Of Analytical Chemistry
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Chapter30: Kinetic Methods Of Analysis
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Problem 30.14QAP
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an a study of the gas phase decomposition of phosphine at 120 °C
PH3(g)1/4 P4(g) + 3/2 H2(g)
the concentration of PH3 was followed as a function of time.
It was found that a graph of In[PH3] versus time in seconds gave a straight line with a slope of -2.81×10-2 s1 and a y-intercept of -4.31.
Based on this plot, the reaction is
| order in PH3 and the rate constant for the reaction is
s1.
Transcribed Image Text:an a study of the gas phase decomposition of phosphine at 120 °C PH3(g)1/4 P4(g) + 3/2 H2(g) the concentration of PH3 was followed as a function of time. It was found that a graph of In[PH3] versus time in seconds gave a straight line with a slope of -2.81×10-2 s1 and a y-intercept of -4.31. Based on this plot, the reaction is | order in PH3 and the rate constant for the reaction is s1.
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