On the basis of the 18-electron rule, identify the first-row transition metal for each of the following: a. [M(CO);1+ b. H;CM(CO); c. M(CO),(CS)(PPh,)Br d. [(7-C,H)(n-C;H;)M(CO)]

Principles of Instrumental Analysis
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Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Chapter14: Applications Of Ultraviolet-visible Molecular Absorption Spectrometry
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( do 1st four asap within 30 min )
On the basis of the 18-electron rule, identify the first-row
transition metal for each of the following:
а. [MСО
b. H;CM(CO);
c. M(CO),(CS)(PPh;)Br
d. [(7-C,H;(7-C,H;)M(CO)]
OCH3
e.
(OC),M=C
CH5
f. [(n-C,H)(7-C;Hs)M]*
g. (7-C,H;X7-C;H;)M(CH;)(NO) (has linearly coor-
dinated NO)
h. [M(CO),I(diphos)]
(diphos
1,2-bis(diphenylphosphino)ethane)
Transcribed Image Text:On the basis of the 18-electron rule, identify the first-row transition metal for each of the following: а. [MСО b. H;CM(CO); c. M(CO),(CS)(PPh;)Br d. [(7-C,H;(7-C,H;)M(CO)] OCH3 e. (OC),M=C CH5 f. [(n-C,H)(7-C;Hs)M]* g. (7-C,H;X7-C;H;)M(CH;)(NO) (has linearly coor- dinated NO) h. [M(CO),I(diphos)] (diphos 1,2-bis(diphenylphosphino)ethane)
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