| Complete the data table below. Concentration of HA pH [H]= X from an ice Percent Ionization table 238 Y1.00 M 2) 2.87 3Y 3.38 4 3.86 4.39 Note: pHAog[H"] or 10 pH = [H"]
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Solution :
I- Initial concentration
C - Change
E -Equilibrium
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- By the use of Henderson Hasselbalch equation; pH = pKa + log{[acetate ion]/[acetic acid]} 4.5 = 4.75 + log{[0.10 M]/[acetic acid]} -0.25 = log{[0.10 M]/[acetic acid]} [Acetic acid] = 0.10 M/ 10-0.25 [Acetic acid] = 0.10 M/0.56 [Acetic acid] = 0.1786 M Moles of sodium acetate dissolved in 250 mL buffer solution = 0.10 M× (250mL/1000mL) × 1L = 0.025 mol Weight (w) of sodium acetate (purity 100%) dissolved to prepare 250 mL of solution with buffer concentration of 0.10 M is calculate as follow; w100% = 0.025 mol × 82.0343 g/mol = 2.051 g Weight (w) of sodium acetate (purity 99%) is calculate as follow; w99% = 2.051 g× (100/99) = 2.072 g What was the volume of 6.12 M acetic acid HC2H3O2 needed to prepare the 250 mL acetic acid/acetate ion buffer solution required in this part? Show your calculations.Q1. Dissolved 0.273 grams of pure sodium oxalate (Na2C0.) In distilled water and added sulfuric acid and titration the solution at 70 ° C by using 42.68 ml of KMnO, solution and has exceeded end point limits by using 1.46 ml of oxalic acid (H , C, 0.) With 0.1024 N. Calculate the normlity of KMnO .. Note that the molecular weight of sodium oxalate (Na, C, 0.) = 134 and its equivalent weight = 67Using an experimentally determined value (2.5×10−10) of Ksp, determine the value for the reaction quotient 'Q' if Ag2CrO4 will precipitate when 7.00 mL of 0.0040 M AgNO3 are added to 5.00 mL of 0.0024 M K2CrO4.
- Q1. Dissolved 0.273 grams of pure sodium oxalate (Na,C,O.) in distilled water and added sulfuric acid and titration the solution at 70 ° C by using 42.68 ml of KMNO, solution and has exceeded end point limits by using 1.46 ml of standard oxalic acid (H; C;O.) with 0.1024 N. Calculate the normlity of KMN0.. Note that the molecular weight of sodium oxalate (Na,C,O.) = 134 and its equivalent weight = 67Consider a saturated solution of barium iodate in 0.025 M BaCl2. For the salt: Ba(IO3)2(s) ⇌ Ba2+ + 2IO3- Ksp = 1.57 \times× 10-9 at 25 deg C What is the activity coefficient of Ba2+? Consider a saturated solution of barium iodate in 0.025 M BaCl2. For the salt: Ba(IO3)2(s) ⇌ Ba2+ + 2IO3- Ksp = 1.57 × 10-9 at 25 deg C What is the activity coefficient of Ba2+?. 0.439 0.364 0.276 0.405Compare and contrast an anticipatory standard to a reactionary standard by listing and describing some advantages and disadvantages.
- Hexanoic acid was added to an immiscible biphasic solvent sysem, water and CCl4 at 20.0OC and the equilibrium concentrations of hexanoic acid were determined to be 3.66 g/L in H2O and 67.0 g/L in CCl4. Caluclate the distrubution coeffiecent (D1) of hexanoic acid in CCl4 with respect to water.Calculate the solubility of lead(II) sulfate (Ksp = 2.53x10-8) in a 0.0034 M solution of sodium sulfate. Give your answer to three sig. figs. and in exponential form (e. g. 1.23E-3).If 30.0 mL of water that is 0.0500 M in Q is to be extracted with four 10.0 mL portions ofan immiscible organic solvent, what is the minimum distribution coefficient that allowstransfer of all but 1.00 x 10–4 of the solute to the organic layer.
- 00 mL of a diprotic acid primary standard solution was accurately prepared to a concentration of 0.1431 M. Three samples of this primary standard solution were used as samples in a titration to standardize an aqueous solution of sodium hydroxide, NaOH, which would be used as a titrant. Using the following table of data for the titration of the primary standard acid with NaOH, calculate the average concentration of NaOH. Trial # Volume of primary standard Initial titrant volume Final titrant volume 1 10.00 mL 8.21 mL 27.22 mL 2 10.00 mL 27.22 mL 46.23 mL 3 10.00 mL 30.28 mL 49.29 mL 0.1506 M 0.0753 M 0.0376 M 0.1431 M 0.0526 MIn an experiment to determine the concentration of H2SO4 in a brand of toilet cleanser, 10.0 cm3 of the cleanser was first diluted to 250.0 cm3 with distilled water. 25.0 cm3 of the diluted cleanser were titrated with 0.320 mol dm–3 NaOH solution, using methyl orange as indicator.If 29.2 cm3 of NaOH solution is used, what is the concentration of H2SO4 in the undiluted toilet cleanser?a. 2.30 mol dm–3b. 4.60 mol dm–3 c. 9.20 mol dm–3 d. 11.50 mol dm–3Dissolved 0.273 grams of pure sodium oxalate (Na2C204) in distilled water and added sulfuric acid and titration the solution at 70 °C by using 42.68 ml of KMNO4 solution and has exceeded end point limits by using 1.46 ml of standard oxalic acid (H2 C204) with 0.1024 N. Calculate the normlity of KMNO4. Note that the molecular weight of sodium oxalate (Na2C204) = 134 and its equivalent weight = 67 * %3D