Reaction Conc, Nagd 0, Cone. HCI Als. I Rabe 11.3 0 85840 65.56796607 5. 1143/471 AIme (3) 0.10 M • 30M 0.4563/64 0.028 F0913 .15 M A2267196|0.01870913 30M 1.5360817 0.300349 0.30M 1.507661 0.10 M 3 0.050 M 4 0.025 M 1.007568 1,359380874 3. What is the overall order of the reaction? Write the complete rate law for this reaction.

Principles of Instrumental Analysis
7th Edition
ISBN:9781305577213
Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Chapter34: Particle Size Determination
Section: Chapter Questions
Problem 34.5QAP
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Readion Cone, Nay S0, Cine HCI|Ab. 1 | Rabe
I1.3085840
65.56796607
Cone, Nagd, 03
ATme (5)
0.10 M
·30M 04563164 |0.028 F09 13
,15 M 12267196|0.01870913
30M |1.5360817 0.300349
O.10 M
3
0.050 M
5. 11431671
4
0.025 M
0:30M
1.3686611
1,358380874
1.007568
3. What is the overall order of the reaction? Write the complete rate law for this reaction.
Transcribed Image Text:Readion Cone, Nay S0, Cine HCI|Ab. 1 | Rabe I1.3085840 65.56796607 Cone, Nagd, 03 ATme (5) 0.10 M ·30M 04563164 |0.028 F09 13 ,15 M 12267196|0.01870913 30M |1.5360817 0.300349 O.10 M 3 0.050 M 5. 11431671 4 0.025 M 0:30M 1.3686611 1,358380874 1.007568 3. What is the overall order of the reaction? Write the complete rate law for this reaction.
Expert Solution
Step 1

Rate=K[A]m[B]n Considering Reaction 1 and reaction 2rate1rate2=K(0.10)m(0.30)nK(0.10)m(0.15)n11.308584065.56796607=2ncalculating the value of n, taking ln on both the sidesln(0.17)=nln2dividind both sides by ln2n=ln(0.17)ln(2)n=-2.5Note:Order can never be negative but order w.r.t to specific reactant can be negative

Considering reaction 3 and 4rate3rate4=K[A]m[B]nK[A]m[B]n5.114316711.358380874=[0.050]m[0.025]mcalculating the value of mIn similar way find the value of m as calculated for n 

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