Select the metal centre with d2sp3 hybridization. a.[Rh(acac)3] b.[RuMe2(bpy)2] c.[RhCl3(PMe3)] d.[Ru(acac)2(H2O)2]

Q: [Ni (NH3) 6] C12 Explain the hybridization, geometry and magnetic property of the complex structure.

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Q: Use the angular overlap method to calculate the metal d-orbital energies for trans-[Cr(NH4);Cl2]*.

A: trans-[Cr(NH4)3Cl2]+ it has trans-octahedral structure.NH3 group is σ donor and Cl is π donor.The…

Q: According to the valence bond theory, which of the following statements is/are incorrect? (79Au) I-…

A: Outer orbital complexes are formed when outer d orbitals along with s and p orbitals are involved in…

Q: Draw combinations of orbitals by using all three p orbitals of atom A and all five d orbitals of…

A: The region in the three-dimensional space of an atom and it has a greater probability of finding an…

Q: Which method of the following may be used to distinguish between the two [Co(NH3)s(NO2)]CI linkage…

A: IR spectroscopy is used to identify the functional group in a molecule as different functional group…

Q: Draw the hybridization for the metal centre of the complex below. You need to determine the geometry…

A: Hybridization is the process of mixing up of atomic orbitals to give new orbitals, hybrid orbitals.…

Q: 7. MO Diagram. Consider the molecule [Cr(CO)6]²*. e) bonding (nb), and antibonding (*) orbitals,…

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Q: addition of S2- ion to Fe(OH)2(s) results in the formation of FeS(s). Explain why the addition of…

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Q: Determine the type of hybrid orbitals and the spatial structure of the following two complexes. A)…

A: A) Atomic number of Fe is 26. Electronic Configuration of Fe is [Ar]3d64s2 Electronic Configuration…

Q: Many compounds of the transition-metal elements contain direct bonds between metal atoms. We will…

A: Hello. Since the question contains multiple sub-parts, the first three subparts are solved. In case…

Q: Which of the following is paramagnetic? [Zn(H₂0)6]²+ [Cu(H₂0)6]* Onone of these [Co(NH3)6]³+ (strong…

A: “Since you have asked multiple question, we will solve the first question for you. If youwant any…

Q: Q 1: Iron as for a transition metal and it can adopt different oxidation states.One of the most…

A: Since you have asked multiple question, we will solve the first question for you.If you want any…

Q: In which of the following cases all complexes are square planes? (27Co, 28Ni, 46Pd, 78Pt, 79Au)…

A: Coordination complexes  with coordination number 4 can be either tetrahedral or square planar.…

Q: According to the Valence Bond Theory [CoCl6] 3-complex ion has 4 unpaired electrons. Accordingly,…

A: Explained as follows

Q: According to the Valence Bond Theory [CoCl6]3-complex ion has 4 unpaired electrons. Accordingly,…

A: complex salts are made of complex ions or  complex neutral molecule , in which central metal atom is…

Q: 4 Illustrate how complex formation between Fe3+ and SCN Occurs by presenting electrons by arrows (1)…

A: This question is related to coordination chemistry.  Coordination cplexes are the compounds…

Q: According to the valence bond theory, which of the following statements is/are incorrect? (79Au) I-…

A: Outer orbital complexes are coordinate compounds consisting of a central metal atom which undergoes…

Q: NiCl4]2- and Ni(CO)4 have sp3 or dsp2 hybridization? Explain. What type of hybridization is shown by…

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Q: Theory [CoCl6] 3-complex ion has 4 unpaired electrons. Accordingly, which of the following…

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Q: Using valence bond theory, explain the following in relation to the complex given below [Cr (CO)6]…

A: VSEPR theory is Valence Shell Electron Pair Repulsion theory.  It helps to find out the…

Q: According to the valence bond theory, which of the following statements is/are incorrect? (79Au) I-…

A: Hajaj

Q: Which of the following will exhibit cis-trans isomerism? Fe°: [Ar]4s?3d6 Cdº: [Kr]5s²4d10 Pt0:…

A: Option D; All of the above

Q: i. Define dr-pr bonding. ii. Why C=N can accept the electron from the dn orbital in metal central?

A: i. Sometimes some 3rd period elements like Cl, S, P etc. and some transition metals shows dπ-pπ…

Q: Which metal center does not obey the 18-electron rule? a. Fe in Fe(n5-C5H4COME)2 b. Co in Co2(CO)8…

A: 18-electron rule: It is also known as EAN(Effective atomic number rule). This rule is generally…

Q: 29. For each of the following ions, draw diagrams like those in Figure 8.18 to show orbital…

A: Here, the orbital energy splitting diagram has to be drawn for given ions in both the weak and…

Q: 3) The molecule [CuFaJK, has a unique structure (due to jahn-teller distortion) where it has an…

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Q: Coordination Geometries Linear L Bent B Trigonal Planar TP Trigonal Pyramidal TPy…

A: The possible geometries of SO32- are,

Q: The Ag+ ion is larger in a square planar environment than it is in a tetrahedral one. For Ni+2 the…

A: The Ag+ ion is larger in a square planar environment

Q: how can I explain the complex trans – [CoBr2(en)2] by valence bond theory

A: VBT is the valence bond theory which describes the bonding of the complex in the coordination…

Q: Select the metal centre with d2sp3 hybridization. О а. [Rh(acac)3] O b. [Ru(acac)2(H2O)2] Ос.…

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Q: What do you understand by the following types of stacking sequences:(a) AB AB ............... (b) A…

A: Stacking sequence is used to describe the arrangement of atoms present in layers in crystal lattice.…

Q: When the hybrid type, geometry and magnetic properties of the hexaaminnikel (II) chloride complex…

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Q: 9. Which of the following statements is incorrect? A. Based on its Lewis structure, oxygen molecule…

A: Molecular orbital theory is used to describe the structure of a molecule by identifying the orbitals…

Q: Which of Au(NO3) and AuI would be expected to be more reactive? Explain your reasoning

A: Following salt is more reactive according to electrochemical series.

Q: How many delectrons (nof dn) are in the central metal ionin (a) Ca[IrF6]; (b) [HgI4]2-; (c)…

A: a) Ca[IrF6]  First find the oxidation state of Ir in Ca[IrF6] The sum of the oxidation number of…

Q: The molecule (CuFeJKa has a unique structure (due to jahn-teller distortion) where it has an…

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Q: What chemical change is responsible for the yellow solution observed during the qualitative test for…

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Q: Draw a complete molecular orbital diagram for 1,3,5,7-octatetraene including: Labeled y-axis. MO…

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Q: When solid Cu(CN)2 was ablated with 1064 nm laser pulses, various ions containing 2-coordinate Cu2…

A: Given: When solid Cu(CN)2 was ablated with 1064 nm laser pulses, various ions containing…

Q: (1I) According to the valence bond theory (VBT) answer the following regarding to [NicIj? complex.…

A: Nickel has 28 Electrons, electronic configuration of 1s2,2s2,2p6,3s2,3p6,4s2, 3d8. While Ni2+ ion…

Q: Show how Mn2+ and Gd3+ are paramagnetic.

A: Paramagnetic :  An element that contains an unpaired electron such element shows paramagnetic…

Q: wo researchers are to produce non-ferrous alloys materials. Researcher A is producing cast lloys…

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Q: (a) What coordination geometries could [AuI4]− take and how might it differ from the [AuCl4]− ion?

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Q: Draw the hybridization for the metal centre of the complex below

A: According to Valence bond theory: Electrons in a molecule occupy atomic orbitals rather than…

Q: a) Transition metal complexes are highly likely to be colored because of the size of the energy gap…

A: Since you have asked multiple questions, we will answer the first one for you. To get the remaining…

Q: H H - N - H H C- H H - N - C-H | H-C- F: (CH3)2NH CH3NH2 NH3 NF3

A: Welcome to bartleby ! We have to tell the steric number and coordination geometry of central atom

Q: Draw and fill the molecular orbitals for CO (assume weak sp interactions).

A: The energy of filling of molecular orbitals in the CO molecule is in the order:…

Q: [Fe(CN)6]3- ion has magnetic moment of 1.73 B.M. whereas [Fe(H2O)6]3+ has a magnetic moment of 5.92…

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Atomic Structure

The basic structure of an atom is defined as the component-level of atomic structure of an atom. Precisely speaking an atom consists of three major subatomic particles which are protons, neutrons, and electrons. Many theories have been stated for explaining the structure of an atom.

Shape of the D Orbital

Shapes of orbitals are an approximate representation of boundaries in space for finding electrons occupied in that respective orbital. D orbitals are known to have a clover leaf shape or dumbbell inside where electrons can be found.