When solid Cu(CN)2 was ablated with 1064 nm laser pulses, various ions containing 2-coordinate Cu2 bridged by cyanide ions were formed. These ions collectively have been dubbed a metal cyanide “abacus.” What are the likely structures of such ions, including the most likely geometry around the copper ion? (See I. G. Dance, P. A. W. Dean, K. J. Fisher, Inorg. Chem., 1994, 33, 6261.)
When solid Cu(CN)2 was ablated with 1064 nm laser pulses, various ions containing 2-coordinate Cu2 bridged by cyanide ions were formed. These ions collectively have been dubbed a metal cyanide “abacus.” What are the likely structures of such ions, including the most likely geometry around the copper ion? (See I. G. Dance, P. A. W. Dean, K. J. Fisher, Inorg. Chem., 1994, 33, 6261.)
Physical Chemistry
2nd Edition
ISBN:9781133958437
Author:Ball, David W. (david Warren), BAER, Tomas
Publisher:Ball, David W. (david Warren), BAER, Tomas
Chapter14: Rotational And Vibrational Spectroscopy
Section: Chapter Questions
Problem 14.96E
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When solid Cu(CN)2 was ablated with 1064 nm laser pulses, various ions containing 2-coordinate Cu2 bridged by cyanide ions were formed. These ions collectively have been dubbed a metal cyanide “abacus.” What are the likely structures of such ions, including the most likely geometry around the copper ion? (See I. G. Dance, P. A. W. Dean, K. J. Fisher, Inorg. Chem., 1994, 33, 6261.)
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