со,н Со,н O,N- -со-н O,N-

Introduction to General, Organic and Biochemistry
11th Edition
ISBN:9781285869759
Author:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Publisher:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Chapter3: Chemical Bonds
Section: Chapter Questions
Problem 3.57P: 3-57 What is: (a) A single bond? (b) A double bond? (c) A triple bond?
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Rank the following compounds in order of increasing acidity, and explain in detail your choice of order.

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Transcribed Image Text:со,н Со,н O,N- -со-н O,N-
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Step 1

Chemistry homework question answer, step 1, image 1

NO2 is an electron withdrawing group and it is bonded directly to benzene ring which further is bonded to carbonyl group. Inductive effect and resonance effect of NO2 stabilizes the conjugate base.

Step 2

Chemistry homework question answer, step 2, image 1

Here carbonyl group is not directly bonded to benzene ring only electrons withdrawing –I effect of NO2 stabilize the conjugate base. So E has intermediate acidity.

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