Suppose a change (an error, if you like) was made in the procedure of the experiment. We would to know qualitatively, (higher than the correct value, lower than the correct value, or no change) how this change would affect the calculated hydroxide ion concentration. A suggested method for determining and explaining the answer was given in experiment 7 and is repeated here for one such change, with only the final conclusion missing. Fill it in. For the second change, you do the whole analysis. Change 1 – The endpoint was overshot (too much titrant was added). Quantity Measured value (what actually happened) “True” value (what should have happened) (Compared to true value) measured value is Why? Initial burette reading Correct Beginning of titration was ok. Final burette reading 31 mL, say 30 mL, say Too high VNaOH Too high so change in the same direction. Correct Pipetting was ok. Correct Too _________ The numerator is correct; the denominator too high. Change 2 – When pipetting the HCl solution, instead of just touching the tip to the surfaceof the liquid, you forcibly expelled the last bit of solution in the pipette.

Principles of Modern Chemistry
8th Edition
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Chapter15: Acid–base Equilibria
Section: Chapter Questions
Problem 102AP
icon
Related questions
icon
Concept explainers
Question
Suppose a change (an error, if you like) was made in the procedure of the experiment. We would to know qualitatively, (higher than the correct value, lower than the correct value, or no change) how this change would affect the calculated hydroxide ion concentration. A suggested method for determining and explaining the answer was given in experiment 7 and is repeated here for one such change, with only the final conclusion missing. Fill it in. For the second change, you do the whole analysis. Change 1 – The endpoint was overshot (too much titrant was added). Quantity Measured value (what actually happened) “True” value (what should have happened) (Compared to true value) measured value is Why? Initial burette reading Correct Beginning of titration was ok. Final burette reading 31 mL, say 30 mL, say Too high VNaOH Too high so change in the same direction. Correct Pipetting was ok. Correct Too _________ The numerator is correct; the denominator too high. Change 2 – When pipetting the HCl solution, instead of just touching the tip to the surfaceof the liquid, you forcibly expelled the last bit of solution in the pipette.
Expert Solution
trending now

Trending now

This is a popular solution!

steps

Step by step

Solved in 4 steps

Blurred answer
Knowledge Booster
Ionic Equilibrium
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
  • SEE MORE QUESTIONS
Recommended textbooks for you
Principles of Modern Chemistry
Principles of Modern Chemistry
Chemistry
ISBN:
9781305079113
Author:
David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:
Cengage Learning
Fundamentals Of Analytical Chemistry
Fundamentals Of Analytical Chemistry
Chemistry
ISBN:
9781285640686
Author:
Skoog
Publisher:
Cengage