The 2D particle in a box model can be used to describe the spectra of aromatic hydrocarbons. Assume a rectangular box that extends one bond length beyond the carbon atoms to contain the hydrogen atoms in the box. Hint: You will have to use some trigonometry basics to get the relevant dimensions. Calculate the first three electronic transitions for pyrene (bond length 1.42 Angstroms).

Physical Chemistry
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ISBN:9781133958437
Author:Ball, David W. (david Warren), BAER, Tomas
Publisher:Ball, David W. (david Warren), BAER, Tomas
Chapter15: Introduction To Electronic Spectroscopy And Structure
Section: Chapter Questions
Problem 15.58E
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The 2D particle in a box model can be used to describe the spectra of aromatic
hydrocarbons. Assume a rectangular box that extends one bond length beyond the
carbon atoms to contain the hydrogen atoms in the box. Hint: You will have to use
some trigonometry basics to get the relevant dimensions.
Calculate the first three electronic transitions for pyrene (bond length 1.42
Angstroms).
Transcribed Image Text:The 2D particle in a box model can be used to describe the spectra of aromatic hydrocarbons. Assume a rectangular box that extends one bond length beyond the carbon atoms to contain the hydrogen atoms in the box. Hint: You will have to use some trigonometry basics to get the relevant dimensions. Calculate the first three electronic transitions for pyrene (bond length 1.42 Angstroms).
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