The progress of the reaction between Iodine ions and potassium iodate(V) can be followed by withstanding samples of the reaction mixture at various times, quenching and then titrating with standard thiosulphate solution. The reaction equation is: I(aq) + IO3(aq) + 6H+(aq) + 4e  ➡  I2(aq) +  3H2O(l) In one such experiment the following data were obtained. (see figure

Physical Chemistry
2nd Edition
ISBN:9781133958437
Author:Ball, David W. (david Warren), BAER, Tomas
Publisher:Ball, David W. (david Warren), BAER, Tomas
Chapter20: Kinetics
Section: Chapter Questions
Problem 20.38E: List at least four experimentally determined parameters that you, an experimenter, can define when...
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The progress of the reaction between Iodine ions and potassium iodate(V) can be followed by withstanding samples of the reaction mixture at various times, quenching and then titrating with standard thiosulphate solution. The reaction equation is:

I(aq) + IO3(aq) + 6H+(aq) + 4e  ➡  I2(aq) +  3H2O(l)

In one such experiment the following data were obtained. (see figure below)

  • Determine the order of the reaction with respect to I(aq) and IO3(aq) ions 
  • Write the rate expression for the reaction.

 

initial reaction
Inital Concentration (mol dm) of
(aq)
0.019
0.038
Rate/mo! dm³s1
KIO (aq)
0.015
1
3.5 x 106
7.0 x 106
28.0 x 106
0.015
0.038
0.030
Transcribed Image Text:initial reaction Inital Concentration (mol dm) of (aq) 0.019 0.038 Rate/mo! dm³s1 KIO (aq) 0.015 1 3.5 x 106 7.0 x 106 28.0 x 106 0.015 0.038 0.030
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ISBN:
9781133958437
Author:
Ball, David W. (david Warren), BAER, Tomas
Publisher:
Wadsworth Cengage Learning,