*23-15. The molar absorptivity for the complex formedbetween bismuth(III) and thiourea is 9.32 X 10³L mol-1 cm-1 at 470 nm. Calculate the range ofpermissible concentrations for the complex ifthe absorbance is to be no less than 0.15 norgreater than 0.80 when the measurements aremade in 1.00-cm cells.23-16. The molar absorptivity for aqueous solutions ofphenol at 211 nm is 6.17 × 10³ L mol- cm-!.Calculate the permissible range of phenol con-centrations that can be used if the transmittanceis to be less than 80% and greater than 5% whenthe measurements are made in 1.00-cm cells.

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Fundamentals Of Analytical Chemistry

9th Edition

ISBN:9781285640686

Author:Skoog

Publisher:Skoog

Chapter26: Molecular Absorption Spectrometry

Section: Chapter Questions

Problem 26.5QAP

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The accompanying data (1.00-cm cells) were obtained for the spectrophotometric titration 10.00 mL of Pd(II) with 2.44 10-4 M Nitroso R(O. W Rollins and M. M. Oldham, Anal. chem .,1971, 43, 262, DOI: 10.1021/ac60297a026). Calculate the concentration of the Pd(II) solution, given that the ligand-to-cation ratio in the colored product is 2:1
At 580 nm, which is the wavelength of its maximum absorption, the complex Fe(SCN)2+ has a molar absorptivity of 7.00 I03L cm-1 mol-1.Calculate (a) the absorbance of a 4.47 10-5 M solution of the complex at 580 nm in a 1.00-cm cell. (b) the absorbance of a solution in a 2.50-cm cell in which the concentration of the complex is one half that in(a). (c) the percent transmittance of the solutions described in (a) and (b). (d) the absorbance of a solution that has half the transmittance of that described in (a).
The molar absorptivity (ε) of the FeSCN2+ complex ion is 4700 M-1 · cm-1 at a wavelength of 450 nm. Using a 1-cm sample tube, you measure the absorbance as (2.0x10-1). What is the concentration of FeSCN2+?
A green solution containing Ni+2 ions absorbs 580 nm light. Undiluted, a sample of this solution sampled in a 1.00 cm diameter cuvette has an absorbance of 0.9765 a.u.. If the molar absorptivity coefficient for Ni+2 is 6.3 x 104 M -1 cm -1 at 580 nm, how much of the original stock Ni+2 solution (in mL) needs to be added to water to create a total dilute solution volume of 10.00 mL that measures an absorbance of 0.146 a.u. at 580 nm? Report your answer to 3 significant figures. Do not include the "mL' unit label in your response
A standard solution was put through appropriate dilutions to give the concentrations of iron shown in the table that follows. The iron(II)-1,10-phenanthroline complex was then formed in 25.0-mL aliquots of these solutions, following which each was diluted to 50.0 mL. The following absorbances (1.00-cm cells) were recorded at 510 nm: Calculate the concentration, in ppm, of a sample with an abosrbance of 0.829. Fe(II) concentration (ppm) A510 4.00 0.160 10.0 0.390 16.0 0.630 24.0 0.950 32.0 1.260 40.0 1.580
A solution of Tryptophan has an absorbance at 280 nm of 0.54 in a 0.5 cm length cuvette. Given the absorbance coefficient of trp is 6.4 x 103 Lmol-1cm-1. What is the concentration of solution?
Calculate for the molar absorptivity coefficient of a 0.55 microgram per liter Cr(III) chelate solution that exhibits an absorbance of 0.9765 at 590 nm measured in a 1.00 cm cell.
A (0.002M) Cu2+ solution gave an absorbance of 0.50 at 560 nm in a 1.0 cm cell. The molar absobitivity of solution is equel:
The absorbances of solutions containing K2CrO4 in 0.05 M KOH were measured in a 1.0-cm cell of 375 nm. The following results were obtained: Calculate the concentration of K2CrO4 (g/L) if the A is 0.550.
A FeSCN complex, whose maximum absorbance is at a λ of 580 nm, has a molar extinction coefficient of 5×103 M-1cm-1 . A solution is measured with a 25 mm cell at the same λ , obtaining 20.6% T. Calculate the concentration in [ppm] of the complex in the solution.
You are working with metal thiocyanate complex, M(SCN)+, with a molar absorptivity constant, ε, of 2700 cm−1M−1 at 500 nm. If you are is using a 1.00 cm cuvette for absorbance measurements at 500 nm, what concentration of M(SCN)+ will give an absorbance value of 0.280?
Calculate the absorbance at 280 nm that is expected for a 17 microM solution of peptide GRAYISH, if a 10-cm cuvette is used. For the extinction coefficient, take into account that e280(Trp) = 5690 M-1 cm-1 and e280(Tyr) = 1280 M-1 cm-1.

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