The organic compound 18-crown-6 (see preceding prob- lem) also binds strongly with the alkali metal ions in methanol. K* + 18-crown-62[complex]* In methanol solution the equilibrium constant is 1.41 × 106. A similar reaction with Cs* has an equilibrium con- stant of only 2.75 × 10ª. A solution is made (in methanol) containing 0.020 mol L-1 each of K* and Cs+. It also contains 0.30 mol L-1 of 18-crown-6. Compute the equi- librium concentrations of both the uncomplexed K* and the uncomplexed Cs*.
The organic compound 18-crown-6 (see preceding prob- lem) also binds strongly with the alkali metal ions in methanol. K* + 18-crown-62[complex]* In methanol solution the equilibrium constant is 1.41 × 106. A similar reaction with Cs* has an equilibrium con- stant of only 2.75 × 10ª. A solution is made (in methanol) containing 0.020 mol L-1 each of K* and Cs+. It also contains 0.30 mol L-1 of 18-crown-6. Compute the equi- librium concentrations of both the uncomplexed K* and the uncomplexed Cs*.
Principles of Modern Chemistry
8th Edition
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Chapter16: Solubility And Precipitation Equilibria
Section: Chapter Questions
Problem 70AP
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