The rate constant of the reaction H2O2(aq) + I−(aq) + H+(aq) → H2O(l) + HIO(aq) is sensitive to the ionic strength of the aqueous solution in which the reaction occurs. At 25 °C, kr = 12.2 dm6 mol−2 min−1 at an ionic strength of 0.0525. Use the Debye–Hückel limiting law to estimate the rate constant at zero ionic strength.

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Chemistry: The Molecular Science

5th Edition

ISBN:9781285199047

Author:John W. Moore, Conrad L. Stanitski

Publisher:John W. Moore, Conrad L. Stanitski

Chapter11: Chemical Kinetics: Rates Of Reactions

Section: Chapter Questions

Problem 113QRT

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The rate constant of the reaction H₂O₂(aq) + I⁻(aq) + H⁺(aq) → H₂O(l) + HIO(aq) is sensitive to the ionic strength of the aqueous solution in which the reaction occurs. At 25 °C, k_r = 12.2 dm⁶ mol⁻² min⁻¹ at an ionic strength of 0.0525. Use the Debye–Hückel limiting law to estimate the rate constant at zero ionic strength.

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