This question has several parts that must be sequentiam the values in listed below instead of the textbook values. Derivation Calculate the equilibrium constant for the following reaction at 1224 K. 12(g) = 2 1(g) The bond length of I2 is 2.67 Å, and the vibrational wavenumber is 214.5 cm-1. The bond dissociation energy of I₂ is 151.0 kJ-mol-1. [Hint: To calculate the degeneracy of the iodine atom in its ground electronic state, note that there is an unpaired electron in the 5p orbital. The degeneracy is given by (2J + 1), where J, the total angular momentum, is given by the sum of the orbital angular momentum and spin angular momentum. (Assume a standard pressure of 1.00 bar and a mass of 126.90 amu for I.)] Step 1 of 11 Provide the equation needed to calculate the translational partition function for the iodine atom. (Use the following as necessary: h, KB, m, 7, T, and V.) (), atrans,I= (2πmk) h³ (2πmkgT) V Step 2 of 11 Substitute numerical values into the equation from Step 1 to calculate the value of the translational partition function for the iodine atom. trans,1 1.704e-3 X Submit

This question has several parts that must be sequentiam the values in listed below instead of the textbook values. Derivation Calculate the equilibrium constant for the following reaction at 1224 K. 12(g) = 2 1(g) The bond length of I2 is 2.67 Å, and the vibrational wavenumber is 214.5 cm-1. The bond dissociation energy of I₂ is 151.0 kJ-mol-1. [Hint: To calculate the degeneracy of the iodine atom in its ground electronic state, note that there is an unpaired electron in the 5p orbital. The degeneracy is given by (2J + 1), where J, the total angular momentum, is given by the sum of the orbital angular momentum and spin angular momentum. (Assume a standard pressure of 1.00 bar and a mass of 126.90 amu for I.)] Step 1 of 11 Provide the equation needed to calculate the translational partition function for the iodine atom. (Use the following as necessary: h, KB, m, 7, T, and V.) (), atrans,I= (2πmk) h³ (2πmkgT) V Step 2 of 11 Substitute numerical values into the equation from Step 1 to calculate the value of the translational partition function for the iodine atom. trans,1 1.704e-3 X Submit

Chemistry: Principles and Practice

3rd Edition

ISBN:9780534420123

Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer

Publisher:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer

Chapter13: Chemical Kinetics

Section: Chapter Questions

Problem 13.67QE

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