When adding two equivalents of HBr to an alkyne, the second bromine will always add to the same carbon as the first bromine. Why?

Principles of Modern Chemistry
8th Edition
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Chapter23: Polymeric Materials And Soft Condensed Matter
Section: Chapter Questions
Problem 26AP
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When adding two equivalents of HBr to an
alkyne, the second bromine will always add
to the same carbon as the first bromine.
Why?
The negative charge of the first bromine
repels the proton
The negative charge of the first bromine
attracts the second bromine
The first bromine creates steric hindrance
around the carbon
The first bromine stabilizes the carbocation
intermediate
The first bromine stabilizes the carboanion
intermediate
Transcribed Image Text:When adding two equivalents of HBr to an alkyne, the second bromine will always add to the same carbon as the first bromine. Why? The negative charge of the first bromine repels the proton The negative charge of the first bromine attracts the second bromine The first bromine creates steric hindrance around the carbon The first bromine stabilizes the carbocation intermediate The first bromine stabilizes the carboanion intermediate
In the hydroboration-oxidation reaction of a
terminal alkyne, the product is...
an alkyne
an aldehyde
O a ketone
an alkene
an alcohol
Transcribed Image Text:In the hydroboration-oxidation reaction of a terminal alkyne, the product is... an alkyne an aldehyde O a ketone an alkene an alcohol
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