Which of the following complexes has the greatest number of unpaired electrons?

Principles of Modern Chemistry
8th Edition
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Chapter8: Bonding In Transition Metal Compounds And Coordination Complexes
Section: Chapter Questions
Problem 31P
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The spectrochemical series is

               I < Br < Cl < F < OH < H2O < NH3 < en < NO2 < CN

Which of the following complexes has the greatest number of unpaired electrons? 

Select one:

A. [Fe(CN)6]4–
B. [Ni(CN)6]4–
C. [Mn(CN)6]4– 
D. Two of the complexes have an equal number of unpaired electrons that are the greatest number of unpaired electrons.
E. [Co(NH3)6]3+
 
The correct answer should be "B," but can someone explain why?
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