Which of the following reactions will give diphenylmethanone? I) Benzoyl chloride + Benzene + AICI3 II) Benzoyl chloride + Phenylmagnesium bromide II) Diphenylmethanol + KMN04 || II I and II I and III

Which of the following reactions will give diphenylmethanone? I) Benzoyl chloride + Benzene + AICI3 II) Benzoyl chloride + Phenylmagnesium bromide II) Diphenylmethanol + KMN04 || II I and II I and III

Organic Chemistry

8th Edition

ISBN:9781305580350

Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Chapter19: Enolate Anions And Enamines

Section: Chapter Questions

Problem 19.68P

See similar textbooks

Related questions

Q: Part C: Provide any intermediate and final product for Each of the following reaction sequences 1)…

Q: (d) 3-Methylpyridine N-oxide reacts with nitric acid and sulfuric acid to produce compound (19).…

A: In organic chemistry, compounds usually follow addition, substitution, or elimination reaction. The…

Q: Consider the following reaction schemes involving the reaction of an imine with an organolithium…

A: Secondary alcohols cab obtained by the reaction of organolithium compound with an aldehyde

Q: MgBr Acid 2

A: Organic reaction.

Q: 18. Suggest a plausible mechanism with structures of the following reaction: Br, H,0 CH3 CH2B.…

A: In the reaction mechanism of the above reaction, first the alkene will attack on the Br2 molecule as…

Q: What reaction sequence would lead to the following transformation? O (1) Na/NH3(1) (2) NaNH2 (3)…

Q: The 1H NMR spectra for two esters with molecular formula C8H8O2 are shown next. Which of the esters…

Q: A solution of acetone [(CH3)2C=O] in ethanol (CH3CH2OH) in the presence of a trace of acid was…

A: Ketones react with alcohol in the presence of acid H+ to form acetal. Acetal contains two alkoxy…

Q: From the lists of available reagents select the one(s) you would use to in a preparation of…

Q: Select the best answer for the most reasonable synthesis of the target molecule below from ethyl…

A: Here we have to predict the most reasonable synthesis method to convert ethyl acetate into…

Q: A solution of acetone [(CH3)2C = O] in ethanol (CH3CH2OH) in the presence of a trace of acid was…

A: IR spectroscopy study the interaction of infrared radiation with matter. Its range for analysis of…

Q: 3. When compound 11 is treated with two equivalents of methansulfonic acid (MSOH) in…

A: The reaction involves 2 molecules of 11 as reactant. The reaction mechanism is drawn below.

Q: Predict the products of the reaction of the below reagents with either acetophenone or…

A: Note: Since you have posted a question with multiple subparts, we will solve the first three…

Q: Which of the following reagents will not undergo a substitution reaction with the benzenediazonium…

A: this a substitution reaction of benzenediazonium chloride salt.

Q: 1) LIAIH4 2) H30+

Q: What is the final major organic product obtained from the following sequence of reactions? (ethoxide…

A: The question is based on the concept of organic reactions. We have to identify the product formed…

Q: III. Synthesis 1. Starting with benzene and any other suitable inorganic reagent, outline a viable…

A: Chloro group is an ortho/para director. Amino group is a meta director. Nitro group is a meta…

Q: 3.) For the following aromatic compounds, please answer the following questions: a.) Which compounds…

A: 3) Given nitration of benzene which is an example of electrophilic aromatic substitution. When one…

Q: 12) Using the conmmpounds in the box, propose a synthesis for compounds 40, 41 and 42. You can use…

A: Among the given reagents NaOH is a base, PCC and Na2Cr2O7 are oxidizing agents, H2SO4 is an acid, Mg…

Q: write mechanism step by step for the reaction ?

A: The mechanism for the given reaction can be drawn as.

Q: Imine and Enamine Mechanisms Provide a complete mechanism to account for the formation of the…

Q: Complete the following retrosynthetic analysis (the final product is shown first, and the initial…

A: Retrosynthetic reaction can be given as :

Q: Which of the following synthetic routes works best for the preparation of the following molecule?…

A: The question is based on the concept of organic reactions. We have to correctly identify the…

Q: 1. Write a detailed reaction mechanism, for the following reactions: (a) Reaction of…

A: There are many mechanisms in organic chemistry such as nucleophilic substitution, nucleophilic…

Q: Rank the following carboxylic acid derivatives from least reactive (left) to most reactive (right)…

A: The reactivity of carboxylic acid derivative is depend upon two factor., Electrophilic nature of…

Q: Specify the reagent you would use in each step of the following synthesis: Br step 1, step 2…

A: Applying concept of organic synthesis.

Q: Correct order of reactivity of following compounds towards Grignard reagent. HO CI (1) ÑO, (II) a.…

A: option d is the correct option II > III >I

Q: CH3 CH3 H2SO4 а. CH3 A CH3 НО. H2SO4 b. CH2OH CH3 CH3 -Br CH3 + HBr с. `CH3 CH3

Q: Arrange the compounds in order of INCREASING reactivity towards bromination. I. Toluene,…

A: Benzene ring under go electrophilic substitution reactions Activating groups increase reactivity…

Q: Tasks Complete the synthetic sequences by drawing products/substrates/reagents in empty spaces in…

Q: N-acetyl-p-benzoquinone imine (NAPQI) is a toxic metabolite of acetaminophen that can lead to liver…

A: We have given the reaction between (N-acetyl-p-benzoquinone imine) (NAPQI) with Liver protein, in…

Q: The following group are ortho-para director.Draw a contributing structure for the…

A: If the electrophile is attack at ortho position, the formed carbocation is stabilized by donating of…

Q: Treatment of a carboxylic acid with triflwergacetic anhydride leads to an unsymmetrical anhydride…

A: unsymmetrical anhydride and ester are formed by reaction of nucleophilic addition to carbonyl group.…

Q: Rank the following carboxylic acid derivatives in decreasing order (most to least) of reactivity…

A: Reactivity of the carboxylic acid derivatives can be based on the ability of the leaving group or on…

Q: Specify the reagent you would use in each step of the following synthesis: step 1 step 2 Reagents…

A: In the above reaction, the aldehyde oxygen is being removed from the reactant to produce the final…

Q: What compound is produced when (CH3)2CHCH2Br is subjected to the following sequence of steps? 1. Mg,…

Q: Show the steps necessary to convert benzene into p-chlorobenzonitrilie, using a diazonium salt at…

A: It is an example of electrophilic aromatic substitution

Q: -3. (a) Provide retrosynthesis corresponding forward reaction for the following compounds : OH (i)…

Q: 1. Answer ALL parts of this question. OH IN Ph Ph 1 Figure Q1 (a) Provide a two-step retrosynthetic…

Q: Propose a mechanism for the conversion of F to toremifene

Q: Which of the methods shown will successfully complete the following synthesis? OH NH 1) 1) PBR3 1)…

A: The solution is given below -

Q: A retrosynthetic analysis of 1 was undertaken suggesting a forward synthesis starting from compounds…

A: We have to synthesize organic compound 1 :

Q: Predict the product for the following sequence of reactions. excess CH,CH,CI 1. KMNO4/NaOH/H2O H2SO4…

A: The above question is an example of mixture of various concepts. In the above reaction, first…

Q: /nich of the following actions will give tert-butoxybenzene? I) Sodium phenoxide + 2-chloro-2-…

A: Williamson ether synthesis: The Williamson ether synthesis is a method of formation of an ether from…

Q: 3. What are the main products of reaction of the following with phenyl magnesium bromide followed by…

A: Since you have posted a question with multiple sub-parts, we will solve the first three subparts for…

Q: showing the flow of electrons. X A. 1. [(CH₂)₂CH)₂NLi 2. CH CH₂CH₂CH₂Br Provide a mechanism for each…

Q: Which of the methods shown will successfully complete the following synthesis? HO, NH 1) 3) 1) PBr3…

A: Some details about reagent used, H2CrO4 oxidise primary alcohol to corboxylic acids. PCC oxidise…

Q: Consider the following reaction schemes involving the reaction of an imine with an organolithium…

A: Non-bulky organolithiums like n-BuLi can undergo halogen exchange reaction as well as nucleophilic…

Q: benzaldehyde 9 H ethyl formate -OCH₂CH3 1. pyrolidine O 2. 3. H₂O* 8 10 ya ii + excess benzaldehyde…

A: Since you have posted a question with multiple sub-parts, we will solve the first three subparts for…

Concept explainers

NMR Spectroscopy

NMR stands for Nuclear Magnetic Resonance in which the study of different molecules is done based on the interaction of radiofrequency electromagnetic radiations with the nuclei of molecules placed in a strong magnetic field. A precise study of spectra of visible light and all bands of electromagnetic radiation is called spectroscopy.

Question

Which of the following reactions will
give diphenylmethanone?
I) Benzoyl chloride + Benzene + AICI3
II) Benzoyl chloride + Phenylmagnesium
bromide
III) Diphenylmethanol + KMN04
III
I and II
I and III

Expert Solution

This question has been solved!

Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.

SEE SOLUTION Check out a sample Q&A here

Step 1

VIEW

Step 2

VIEW

Final answer

VIEW

Step by step

Solved in 3 steps with 3 images

SEE SOLUTION Check out a sample Q&A here

Knowledge Booster

Learn more about

Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.

Similar questions

Arrange the compounds in order of INCREASING reactivity towards bromination. I. Toluene, Nitrobenzene, Iodobenzene, Acetanilide II. Phenol, Acetophenone, Anisole, Chlorobenzene III. Aniline, Benzaldehyde, Benzonitrile, Benzenesulfonic acid
(a) Give a plausible explanation for each one of the following :(i) There are two – NH2 groups in semicarbazide. However, only one such group is involved in the formation of semicarbazones.(ii) Cyclohexanone forms cyanohydrin in good yield but 2, 4, 6-trimethylcyclohexanone does not.(b) An organic compound with molecular formula C9H10O forms 2, 4, – DNP derivative, reduces Tollens’ reagent and undergoes Cannizzaro’s reaction. On vigorous oxidation it gives 1, 2-benzene-di- carboxylic acid. Identify the compound.
Give the major organic product of each reaction of γ‑valerolactone with each of the given six reagents under the conditions indicated. Do not draw any byproducts formed. Reagent 1. NaOH, H2O, heat, then H+, H2O 2. (CH3)2CHCH2CH2OH (excess), H+ 3. (CH3CH2)2NH and heat 4. CH3MgI (excess), ether, then H+/H2O 5. LiAlH4, ether, then H+/H2O 6. DIBAL, toluene, low temperature, then H+/H2O
Sketch and explain the IR, UV, mass, and NMR (1H and 13C) spectroscopy data of Benzonitrile
Illustrate the following reactions giving a chemical equation in each case: (i) Gabriel phthalimide synthesis (ii) A coupling reaction (ii) Hoffmann’s bromamide reaction.
Over the past several decades, chemists have developed a number of synthetic methodologies for the synthesis of steroid hormones. One of these, developed by Lutz Tietze at the Institut für Organische Chemie der Georg-August-Universität, Göttingen, Germany, used a double Heck reaction to create ring B of the steroid nucleus. As shown in the following retrosynthetic analysis, a key intermediate in his synthesis is compound (1). Two Heck reaction disconnects of this intermediate give compounds (2) and (3). Compound (2) contains the aromatic ring that becomes ring A of estrone. Compound (3) contains the fused five- and six-membered rings that become rings C and D of estrone. Q.Propose structural formulas for compounds (2) and (3).
Over the past several decades, chemists have developed a number of synthetic methodologies for the synthesis of steroid hormones. One of these, developed by Lutz Tietze at the Institut für Organische Chemie der Georg-August-Universität, Göttingen, Germany, used a double Heck reaction to create ring B of the steroid nucleus. As shown in the following retrosynthetic analysis, a key intermediate in his synthesis is compound (1). Two Heck reaction disconnects of this intermediate give compounds (2) and (3). Compound (2) contains the aromatic ring that becomes ring A of estrone. Compound (3) contains the fused five- and six-membered rings that become rings C and D of estrone. Q.Name the types of functional groups in estrone
Over the past several decades, chemists have developed a number of synthetic methodologies for the synthesis of steroid hormones. One of these, developed by Lutz Tietze at the Institut für Organische Chemie der Georg-August-Universität, Göttingen, Germany, used a double Heck reaction to create ring B of the steroid nucleus. As shown in the following retrosynthetic analysis, a key intermediate in his synthesis is compound (1). Two Heck reaction disconnects of this intermediate give compounds (2) and (3). Compound (2) contains the aromatic ring that becomes ring A of estrone. Compound (3) contains the fused five- and six-membered rings that become rings C and D of estrone. Q.How many chiral centers are present in estrone?
Over the past several decades, chemists have developed a number of synthetic methodologies for the synthesis of steroid hormones. One of these, developed by Lutz Tietze at the Institut für Organische Chemie der Georg-August-Universität, Göttingen, Germany, used a double Heck reaction to create ring B of the steroid nucleus. As shown in the following retrosynthetic analysis, a key intermediate in his synthesis is compound (1). Two Heck reaction disconnects of this intermediate give compounds (2) and (3). Compound (2) contains the aromatic ring that becomes ring A of estrone. Compound (3) contains the fused five- and six-membered rings that become rings C and D of estrone. Q.Show how your proposals for compounds (2) and (3) can be converted to compound (1). (Note: In the course of developing this synthesis, Tietze discovered that vinylic bromides and iodides are more reactive in Heck reactions than are aryl bromides and iodides.)
Over the past several decades, chemists have developed a number of synthetic methodologies for the synthesis of steroid hormones. One of these, developed by Lutz Tietze at the Institut für Organische Chemie der Georg-August-Universität, Göttingen, Germany, used a double Heck reaction to create ring B of the steroid nucleus. As shown in the following retrosynthetic analysis, a key intermediate in his synthesis is compound (1). Two Heck reaction disconnects of this intermediate give compounds (2) and (3). Compound (2) contains the aromatic ring that becomes ring A of estrone. Compound (3) contains the fused five- and six-membered rings that become rings C and D of estrone. Q. In the course of the double Heck reactions, two new chiral centers are created. Assume in compound (3), the precursor to rings C and D of estrone, that the fusion of rings C and D is trans and that the angular methyl group is above the plane of the ring. Given this stereochemistry, predict the stereochemistry of…
Giving an example for each describe the following reactions :(i) Hofmann’s bromamide reaction(ii) Gatterman reaction(iii) A coupling reaction
A student mixes benzaldehyde with an unknown symmetrical ketone, compound C, in an aqueous sodium hydroxide solution and produces compound D.Based on the 1H NMR of compound D, shown below, predict the structure of compound