Write the names of the following compounds, using the standard nomenclature rules for coordination complexes: (a) [Rh(NH3)¾C12]CI (b) K2[TIC16] (c) MOOCI, (d) [Pt(H2O)4(C,04)]Br2

Q: Draw the structures and give the stock names of complexes that can satisfy the conditon: 1.…

A: Ionization isomers in coordination complexes are identified by the ligands present outside the…

Q: Which ordering correctly describes the tendency of a ligand to direct ligand substitution in a…

A: Trans effect can be defined as the effect of a ligand towards substitution on other ligands which is…

Q: A four coordinate complex MA2B2 is prepared and found to have two different isomers possible to…

A: Four coordinate complex MA2B2:In this complex, there are two types of ligands A and B with number…

Q: The thermodynamic stability of coordination compounds depends on, а. AG¢ b. magnetic susceptibility…

A: The thermodynamic stability of coordination compound depends on the following factors.

Q: Illustrate the Transition-Metal Complexes?

A: Transition metals are d-block elements. These elements can co-ordinate with negative or neutral…

Q: How can know the cis and trans of geometrical isomerism in octahedral complexes?

A: Compounds have the same chemical formula but the different stereochemical structure is called…

Q: How many stereoisomers of a hypothetical six-coordinate complex [M(AA);bc] (where AA is a bidentate…

A: Stereoisomers include Geometrical isomers and Optical isomers. There are two Geometrical isomers…

Q: Given the following coordination compounds; Compound R =[Pt(NH3)«(OH)2]SO4 Compound S=…

A: Isomerism in coordination complexes arises when the molecular formula of the complexes are same but…

Q: Draw the structure of the complex, [Ni(NH3)6][BF4]2, including approximate bond angles (in °).…

A: The objective of the question is to draw the given complex and write the angle and geometry.

Q: In the coordination compound (NH4)2[Fe(OH2)F;], the e is octahedrally coordinated. (a) Based on the…

A: a) The given compound is (NH4)2[Fe(OH2)F5] or [Fe(OH2)F5]2-. The oxidation state of Fe is +3 and it…

Q: Consider the octahedral complexes of Co3+. Complete the following statements. The strong field…

A: The answer is given as follows

Q: A four-coordinate complex MA2B2 is prepared and found tohave two different isomers. Is it possible…

A:

Q: Sketch the structure of the complex in each of the follow- ing compounds and give the full compound…

A: a) The Cis-[Co(NH3)4(H2O)2](NO3)2 complex is cis isomer that means the same ligands come on the same…

Q: Draw the structures and give the stock names of complexes that can satisfy the conditon: 1.…

A: The given condition is: Geometric isomers of anionic complexes containing hexacoordinated Os4+ and…

Q: The complex [COF6]¯ absorbs light at a wavelength of 290 nm. What is the value of the crystal filed…

A:

Q: 2. Red crystalline [NiCl,(PPh,CH,Ph)2] is diamagnetic. On heating to 387 K for 2 hours, a blue-…

A: In this complex, nickel is in +2 oxidation state and it has valence shell electronic configuration…

Q: 2. Give two authentic examples of tetragonal elongated paramagnetic octahedral Cr(IV) complexes by…

A: The two authentic examples of tetragonal elongated paramagnetic octahedral Cr(IV) complexes has to…

Q: Give the systematic name of this coordination compound. Na[Au(CN),] systematic name:

A:

Q: 9 A complex with the composition [MA₂B₂]X₂ is found to have no geometrical isomers. Both A and B are…

A:

Q: Let us consider the following coordination complexes: [Fe(CN6)]3- Deduce from these electronic…

A: Crystal field splitting The splitting of degenerate d-orbitals in presence of ligands is called…

Q: Would you expect the complex [Cu(NH3)4(H2O)2]2+ to have isomers? If yes, what isomers would exist?

A: Yes there will be isomers of the complex [Cu(NH3)4(H2O)2]2+  this is because the H2O ligands can be…

Q: Though both [COF6]3 and [Co(CN)6]³- octahedral complexes, the crystal field stabilization energy…

A: If weak field ligand is present,than no pairing occur and filling of electron occur according to…

Q: For the following coordination complex: {Ni(CN)3H20} Give the name Determine the geometry Give the…

A: Formal charge of CN-=-1Formal charge of H2O=0Oxidation state of Ni,x+3*(-1)+0=-1x=+2Hence, Ni exists…

Q: Werner first published his thoughts concerning the possibiolity of chiral coordination compounds in…

A: Geometrical isomer Geometrical isomer having the same molecular formula and same structure but it…

Q: The molecule dimethylphosphinoethane [(CH3)2PCH2CH2P(CH3)2, which is abbreviated dmpe] is used as a…

A: Formula: C6H16P2. Molar mass: 150.14 g/mol.Density: 900 kg/m3. Boiling point: 180 °C. Open chain…

Q: A coordination compound has been determined to be composed of 18.4% Co, 26.6% NH3, 30.0% SO4 , and…

A: A co-ordination compound is a compound containing a central metal atom bound to ligands. The central…

Q: Give the systematic name for the following coordination compound: CI- .F Со

A: While naming any complex ion, the ligands are always named before the metal ion. If multiple ligands…

Q: Ocatahedral” Cu (II) complexes are often described as having a (4+2)- coordination pattern. Suggest…

A: The central metal copper is attached with the six H2O ligands then this complex will be the…

Q: 8

A:

Q: Write the hybridization and shape of the following complexes: (i) [CO(NH3)6]3+ (ii) [NiCl4]2-…

A: Hybridization involves the mixing up of of atomic orbitals into new hybrid orbitals with different…

Q: 2. It was stated that Co3+ complexes are very stable and the ligands in such complexes are not…

A:

Q: In each the following generalized coordination complexes, M represents the central metal ion and L1,…

A: Two compounds that have the same molecular formula but the different structural representation of…

Q: The maximum absorption for the complex ion [Co(NH3 )6 ] 3+ is located at 470 nm. A) Predict the…

A: The wavelength absorbed by the complex is 470 nm Color of the coordination complex will be…

Q: abilization Energy for the following complexes and classify the complexes as diamagnetic vs…

A: Crystal field stabilization energy (cfse) is the energy of splitting of d- orbital of a metal center…

Q: The coordination complex [Cr(CO)6] forms colorless,diamagnetic crystals that melt at 90 °C. (a) What…

A: (a)

Q: Write the names of the following compounds, using the standard nomenclature rules for coordination…

A: While writing the IUPAC names of the coordination compounds, write the name of the ligands attached…

Q: (a) There are essentially three bonding concepts used to describe the bonding in coordination…

A: Solution: For a given complex we can find type of hybridization and magnetic property of the complex…

Q: 9 A complex with the composition [MA₂B₂]X₂ is found to have no geometrical isomers. Both A and B are…

A: [MA2B2]X2 ->The coordination number of metal is 4.

Q: Describe the makeup of a complex ion, including the natureof the ligands and their interaction with…

A: Complex molecules are a section of inorganic chemistry . A complex is formed when a metal center is…

Q: What kind of isomerism can the following complexes have? [Cd(NH3)2Cl4]SO4 , and [Mn(H2O)2(NH3)3OH]+

A: The exchange of the ions without changing the identity of a complex molecule is called Ionization…

Q: The complex diamminedichloronickel(II), (Ni(NH3)2C12], is paramagnetic and does not have any…

A: When a metal linked with the ligands then it is known as coordination compound.

Q: Consider the following three complexes:(Complex 1) [Co(NH3)5SCN]2+(Complex 2)…

A: Isomers are broadly classified into different types and they are: Geometrical Isomers-They differ…

Q: A complex of the type [M(AA)2X2]n+ is optically active,giving a suitable example. comment on the…

A: If the substances  which is under observation are non-superimposable mirror images of each other and…

Q: A, B, C, and D are four different ligands, draw all possible structures of geometric isomers for…

A: In square - planar complex- All the four ligand are different i.e A, B, C, and DThe complex is Pt…

Q: What type of isomerism is shown by each of the following complexes: (i) [Pt(NH3)2Cl2] (ii)…

A: Isomers are molecules or polyatomic ions with identical molecular formulas that is, same number of…