Application of Spectroscopy: You wish to measure the iron content of the well water on the new property you are about to buy. You prepare a reference standard Fe3+ solution with a concentration of 7.50 x 104 M. You treat 15.0 mL of this reference with HNO, and excess KSCN to form a red complex, and dilute the reference to 55.0 mL. The diluted reference is placed in a cell with a 1.00-cm light path. You then take 15.0 mL of the well water, treat with HNO, and excess KSCN, and dilute to 100.0 mL. This diluted sample is placed in a variable pathlength cell. The absorbance of the reference and the sample solutions match when the pathlength is 1.91 cm. What is the concentration of iron in the well water? For each solution, the zero is set with a blank.

Fundamentals Of Analytical Chemistry
9th Edition
ISBN:9781285640686
Author:Skoog
Publisher:Skoog
Chapter26: Molecular Absorption Spectrometry
Section: Chapter Questions
Problem 26.31QAP
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Application of Spectroscopy:
You wish to measure the iron content of the well water on the
new property you are about to buy. You prepare a reference
standard Fe3+ solution with a concentration of 7.50 x 10-4 M. You
treat 15.0 mL of this reference with HNO, and excess KSCN to
form a red complex, and dilute the reference to 55.0 mL. The
diluted reference is placed in a cell with a 1.00-cm light path. You
then take 15.0 mL of the well water, treat with HNO, and excess
KSCN, and dilute to 100.0 mL. This diluted sample is placed in a
variable pathlength cell. The absorbance of the reference and the
sample solutions match when the pathlength is 1.91 cm.
What is the concentration of iron in the well water?
For each solution, the zero is set with a blank.
Transcribed Image Text:Application of Spectroscopy: You wish to measure the iron content of the well water on the new property you are about to buy. You prepare a reference standard Fe3+ solution with a concentration of 7.50 x 10-4 M. You treat 15.0 mL of this reference with HNO, and excess KSCN to form a red complex, and dilute the reference to 55.0 mL. The diluted reference is placed in a cell with a 1.00-cm light path. You then take 15.0 mL of the well water, treat with HNO, and excess KSCN, and dilute to 100.0 mL. This diluted sample is placed in a variable pathlength cell. The absorbance of the reference and the sample solutions match when the pathlength is 1.91 cm. What is the concentration of iron in the well water? For each solution, the zero is set with a blank.
Expert Solution
Step 1

Absorbance is directly proportional to the concentration of the colored sample as per Lambert-beer's Law.

A=εcl

Where, A = Absorbance, c = concentration, l = path length, ε = Molar extinction coefficient.

Given,

Path length of diluted reference = 1cm.

Path length of sample solution = 1.91cm.

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