ORGANIC CHEMISTRY MASTERINGCHEM ACCESS
9th Edition
ISBN: 9780137249442
Author: Wade
Publisher: INTER PEAR
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Chapter 1, Problem 1.59SP
Give the relationships between the following pairs of structures The possible relationships are as follows same compound, cis-trans isomers, constitutional (structural) isomers, and not isomers (different molecular formula).
- a. CH3CH2CH2CH3 and (CH3)3CH
- b. CH2=CH—CH2Cl and CHCl=OH—CH3
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Based on the molecular formula, determine whether each
compound is an alkane, alkene, or alkyne. (Assume that the hydro-
carbons are noncyclical and there is no more than one multiple
bond.)
a. C5H12
b. C3H6
с. С-Н12
d. C11H22
ISOMERS
A. DIRECTIONS: Examine each of the following pairs of structures and determine what type of isomerism is
present.
CHEMICAL STRUCTURE
CHEMICAL STRUCTURE
TYPE OF STRUCTURAL ISOMERISM
1.
CH3
CH3
CH3-CH2-CH-CH3
CH3-C-CHJ
CHS
2.
CH;CH=CH2
3.
СНЗ-СН2-NH-CH-CH
CH3-NH-CH2-CH2-CH3
4.
CH3-CH2-C
CH3-C
0-CH3
5.
6.
CYAMIDLC2 I
Which of these formulas is(are) not valid for octane?
A. C8H18B. C8H20C. C8H16D. CH3CH2CH2CH2CH2CH2CH2CH3E. CH3(CH2)6 CH3
Chapter 1 Solutions
ORGANIC CHEMISTRY MASTERINGCHEM ACCESS
Ch. 1.2C - a. Nitrogen has relatively stable isotopes...Ch. 1.4 - Draw Lewis structures for the following compounds....Ch. 1.5 - Write Lewis structures for the following molecular...Ch. 1.5 - Circle any lone pairs (pairs of nonbonding...Ch. 1.6 - Use electronegativities to predict the direction...Ch. 1.8 - Prob. 1.6PCh. 1.9B - Draw the important resonance forms for the...Ch. 1.9B - Prob. 1.8PCh. 1.9B - Prob. 1.9PCh. 1.9B - Use resonance structures to identify the areas of...
Ch. 1.10A - Draw complete Lewis structures for the following...Ch. 1.10B - Give Lewis structures corresponding to the...Ch. 1.10B - Prob. 1.13PCh. 1.11 - Compute the empirical and molecular formulas for...Ch. 1.16 - a. Use your molecular models to make ethane, and...Ch. 1.17 - a. Predict the hybridization of the oxygen atom in...Ch. 1.17 - Predict the hybridization geometry and bond angles...Ch. 1.17 - Predict the hybridization, geometry, and bond...Ch. 1.17 - Prob. 1.19PCh. 1.17 - Allene, CH2=C=CH2, has the structure shown below...Ch. 1.17 - 1. Draw the important resonance forms for each...Ch. 1.18B - Prob. 1.22PCh. 1.18B - Two compounds with the formula CH3CH=NCH3 are...Ch. 1.19B - Prob. 1.24PCh. 1.19B - Give the relationship between the following pairs...Ch. 1 - a. Draw the resonance forms for SO2 (bonded OSO)....Ch. 1 - Name the element that corresponds to each...Ch. 1 - Prob. 1.28SPCh. 1 - For each compound, state whether its bonding is...Ch. 1 - a. Both PCl3 and PCl5 are stable compounds Draw...Ch. 1 - Draw a Lewis structure for each species a. N2H4 b....Ch. 1 - Prob. 1.32SPCh. 1 - Prob. 1.33SPCh. 1 - Draw Lewis structures for a. two compounds of...Ch. 1 - Prob. 1.35SPCh. 1 - Some of the following molecular formulas...Ch. 1 - Prob. 1.37SPCh. 1 - Give the molecular formula of each compound shown...Ch. 1 - 1. From what you remember of electronegativities,...Ch. 1 - For each of the following structures, 1. Draw a...Ch. 1 - Prob. 1.41SPCh. 1 - Prob. 1.42SPCh. 1 - Prob. 1.43SPCh. 1 - Prob. 1.44SPCh. 1 - For each pair of ions, determine which on is more...Ch. 1 - Use resonance structures to identify the areas of...Ch. 1 - Prob. 1.47SPCh. 1 - In 1934, Edward A. Doisy of Washington University...Ch. 1 - If the carbon atom in CH2Cl2 were fat. there would...Ch. 1 - Cyclopropane (C3H6, a three-membered ring) is more...Ch. 1 - Prob. 1.51SPCh. 1 - Prob. 1.52SPCh. 1 - In most amines, the nitrogen atom is sp3...Ch. 1 - Predict the hybridization and geometry of the...Ch. 1 - Draw orbital pictures of the pi bonding in the...Ch. 1 - Prob. 1.56SPCh. 1 - Prob. 1.57SPCh. 1 - Which of the following compounds show cis-trans...Ch. 1 - Give the relationships between the following pairs...Ch. 1 - Dimethyl sulfoxide (DMSO) has been used as an...
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- What is a hydrocarbon? What is the difference between a saturated hydrocarbon and an unsaturated hydrocarbon? Distinguish between normal and branched hydrocarbons. What is an alkane? What is a cyclic alkane? What are the two general formulas for alkanes? What is the hybridization of carbon atoms in alkanes? What are the bond angles in alkanes? Why are cyclopropane and cyclobutane so reactive? The normal (unbranched) hydrocarbons are often referred to as straight-chain hydrocarbons. What does this name refer to? Does it mean that the carbon atoms in a straight-chain hydrocarbon really have a linear arrangement? Explain. In the shorthand notation for cyclic alkanes, the hydrogens are usually omitted. How do you determine the number of hydrogens bonded to each carbon in a ring structure?arrow_forwardWhat is the meaning of the term tertiary (3) when it is used to classify alcohols? Draw a structural formula for the one tertiary (3) alcohol with the molecular formula C4H10O.arrow_forwardHow many electron pairs are shared when a triple bond exists between two carbon atoms? What must he the geometric arrangement around the carbon atoms in a triple bond? Draw the Lewis structure of a simple molecule that contains a triple bond.arrow_forward
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- What is the class of organic compound to which the molecule belong? A. H2N B. CH3 HC= CH3 C. CI, CI CI- CH3arrow_forwardDraw an acceptable Lewis structure from each condensed structure, such that all atoms have zero formal charge. a. diethyl ether, (CH3CH2)2O, the rst general anesthetic used in medical proceduresb. acrylonitrile, CH2CHCN, starting material used to manufacture synthetic Orlon bersc. dihydroxyacetone, (HOCH2)2CO, an ingredient in sunless tanning productsd. acetic anhydride, (CH3CO)2O, a reagent used to synthesize aspirinarrow_forwardIII. Draw two isomers for the following compounds, in line structural formula only and name them. 1. Alkane with molecular formula C6H14 2. ● ● . ● Cis isomer (Line structure) ● IUPAC name of cis isomer ● Trans isomer (Line structure) IUPAC name of trans isomer Isomer 1 (Line structure) IUPAC name of Isomer 1 Isomer 2 (Line structure) IUPAC name of Isomer 2 .arrow_forward
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